. 2020 Aug 28;59(18):13442–13452. doi: 10.1021/acs.inorgchem.0c01821

Table 3. Overview of Distribution Ratios for Extraction of Co(II) or Cu(II) by 0.2 mol L^–1 TOMAC in Toluene from 7.9 mmol L^–1 CuCl₂ or 17.0 mmol L^–1 CoCl₂ in LiCl or Different Di- and Trivalent Salts and the Salt Cation Standard State Gibbs Free Energy of Hydration (ΔG_hyd, exp⁰)³².

cation	D_Co(II) at 8.5 mol L^–1 Cl^–	D_Cu(II) at 5.5 mol L^–1 Cl^–	ΔG_hyd,exp⁰ (kJ mol^–1)	ΔG_hyd,exp⁰/z (kJ mol^–1)
Li⁺	(2.1 ± 0.1) · 10³	(2.2 ± 0.1) · 10²	–475	–475
Ca²⁺	(4.8 ± 0.3) · 10²	(4.0 ± 0.2) · 10¹	–1505	–753
Mg²⁺	(5.8 ± 0.3) · 10²	(3.8 ± 0.2) · 10¹	–1830	–915
Al³⁺	(5.2 ± 0.3) · 10²	(4.1 ± 0.2) · 10¹	–4525	–1508

Table 3. Overview of Distribution Ratios for Extraction of Co(II) or Cu(II) by 0.2 mol L–1 TOMAC in Toluene from 7.9 mmol L–1 CuCl2 or 17.0 mmol L–1 CoCl2 in LiCl or Different Di- and Trivalent Salts and the Salt Cation Standard State Gibbs Free Energy of Hydration (ΔGhyd, exp0)32.