Table 2. Experimental details.

Crystal data
Chemical formula	[Ti(C10H13O2)2Cl2]
M r	449.21
Crystal system, space group	Monoclinic, C2/c
Temperature (K)	100
a, b, c (Å)	29.3802 (19), 10.8106 (7), 13.6002 (9)
β (°)	91.214 (3)
V (Å3)	4318.7 (5)
Z	8
Radiation type	Mo Kα
μ (mm−1)	0.67
Crystal size (mm)	0.21 × 0.04 × 0.04
Data collection
Diffractometer	Bruker D8 Venture Photon 2
Absorption correction	Multi-scan (SADABS; Bruker, 2016 ▸)
T min, T max	0.923, 1.000
No. of measured, independent and observed [I > 2σ(I)] reflections	18758, 4007, 3053
R int	0.057
(sin θ/λ)max (Å−1)	0.606
Refinement
R[F 2 > 2σ(F 2)], wR(F 2), S	0.048, 0.106, 1.16
No. of reflections	4007
No. of parameters	250
H-atom treatment	H-atom parameters constrained
Δρmax, Δρmin (e Å−3)	0.43, −0.40

Computer programs: APEX3 (Bruker, 2017 ▸), SAINT (Bruker, 2013 ▸), SHELXT2016 (Sheldrick, 2015a ▸), SHELXL2016 (Sheldrick, 2015b ▸), Mercury (Macrae et al., 2020 ▸) and SHELXTL (Sheldrick, 2008 ▸).