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. 2020 Aug 11;184(2):592–606. doi: 10.1104/pp.20.01049

Table 1. Relative abundance of the contributions of the regions of aliphatics (10–50 ppm), oxygenated aliphatics (57–92 ppm), aromatics (92–165 ppm), and carboxyl groups (165–185 ppm) for each cutin 13C MAS NMR spectrum.

Method Cutin Major Structural Classes Relative Abundance of the 13C MAS NMR Assigned Regions
C=O C=C CHO CH2O (CH2)n
Carboxyls Aromatics Oxygenated Aliphatics Aliphatics
%
Reference 5.1 1.7 5.1 2.6 85.5
Cholinium hexanoate 2 h 4.8 1.6 9.6 3.7 80.0
2 h + TFA 3.9 3.1 10.2 4.7 78.1
15 h 4.7 3.1 10.9 3.9 77.5
170 h 4.7 3.1 9.1 3.9 65.0
BMIM acetate 2 h 5.6 4.0 7.2 3.2 80.0
15 h 5.5 5.5 7.8 3.1 73.5
170 h 5.6 6.5 4.0 3.2 80.6