Table 1. Relative abundance of the contributions of the regions of aliphatics (10–50 ppm), oxygenated aliphatics (57–92 ppm), aromatics (92–165 ppm), and carboxyl groups (165–185 ppm) for each cutin 13C MAS NMR spectrum.
Method | Cutin Major Structural Classes | Relative Abundance of the 13C MAS NMR Assigned Regions | ||||
---|---|---|---|---|---|---|
C=O | C=C | CHO | CH2O | (CH2)n | ||
Carboxyls | Aromatics | Oxygenated Aliphatics | Aliphatics | |||
% | ||||||
Reference | — | 5.1 | 1.7 | 5.1 | 2.6 | 85.5 |
Cholinium hexanoate | 2 h | 4.8 | 1.6 | 9.6 | 3.7 | 80.0 |
2 h + TFA | 3.9 | 3.1 | 10.2 | 4.7 | 78.1 | |
15 h | 4.7 | 3.1 | 10.9 | 3.9 | 77.5 | |
170 h | 4.7 | 3.1 | 9.1 | 3.9 | 65.0 | |
BMIM acetate | 2 h | 5.6 | 4.0 | 7.2 | 3.2 | 80.0 |
15 h | 5.5 | 5.5 | 7.8 | 3.1 | 73.5 | |
170 h | 5.6 | 6.5 | 4.0 | 3.2 | 80.6 |