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. 2020 Jun 2;59(31):12785–12788. doi: 10.1002/anie.202004797

Scheme 2.

Scheme 2

Photochemical deracemization of various 3‐(1′‐alkenylidene)‐pyrrolidin‐2‐ones rac1 upon visible light irradiation in the presence of chiral sensitizer 2 and binding of allene enantiomer ent1 to catalyst 2 (inset).