Table 1.

Optimization of the pore diameter by variation of reaction parameters.

Sample[a]	Template[b]	Swelling agent[c]	n (CTAB)[d] [mmol]	T[e] [°C]	Vp [f] [cm3 g−1]	Ap [g] [m2 g−1]	dp [h] [nm]	Particle diameter[i] [nm]
P1	Pluronic P123	–	0.11	25	0.84	975	2.1	103
P2	Pluronic P123	TMB	0.11	25	1.60	1239	2.8	77
P3	Pluronic P123	cyclohexane	0.11	25	0.86	738	2.5	86
P4	Pluronic P123	pentanol	0.11	25	0.49	888	2.1	54
P5	Pluronic P123	TIB	0.11	25	2.00	1306	5.1	150
P6	Pluronic L121	TIB	0.11	25	1.38	1075	4.2	126
P7	Pluronic F127	TIB	0.11	25	0.55	406	2.9	127
P8	Pluronic 31R1	TIB	0.11	25	1.40	1413	4.2	570
P9	Pluronic P123	TIB	0.11	10	1.01	795	4.7	132
P10	Pluronic P123	TIB	0.11	50	1.42	1259	3.0	37
P11	Pluronic P123	TIB	0.03	25	0.49	875	2.1	no particles
P12	Pluronic P123	TIB	0.30	25	1.23	1197	2.8	109

[a] All particle syntheses were performed using 100 mg of precursor; the procedure corresponds to the synthesis presented in the Experimental Section. [b] Template used in the particle synthesis for generating the pore system. [c] Hydrophobic additive for enlargement of the pore diameter; TMB is 1,3,5‐trimethylbenzene, TIB is 1,3,5 triisopropylbenzene. [d] Amount of CTAB in the reaction solution for the condensation reaction. [e] T is the reaction temperature during condensation reaction [f] V _p is the pore volume calculated by the NLDFT method. [g] A _p is the BET surface area. [h] d _p is the pore diameter determined by the NLDFT‐method. [i] Particle diameter determined from TEM images.