Figure 2.

¹H NMR spectra of CB[8]‐directed homodimers of a) VOMe, c) VNH₂, d) VNMe₂, f) VH, and the equilibrium products of b) a 50/50 mixture of VOMe and VNH₂ homodimers as well as e) a 50/50 mixture of VNMe₂ and VH homodimers. g) The equilibrium constant K obtained from integration analysis displays a correlation with the shape complementarity between end‐groups. h) ROESY NMR spectrum of VNMe₂ and VH homodimer mixture shows a clear cross‐correlation between the N,N‐dimethylamino substituent of VNMe₂ and the phenyl group of VH. The Cl⁻ counterions are omitted for clarity.