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Side‐ and top‐views of the solvated single‐crystal X‐ray structures of the imine‐based cages originating from the reactions of tetraaldehydes L1–L3 and B2 (grey) with R,R‐CHDA (red). For B1, single crystals were only obtained for a pseudo‐C 3h‐symmetric structure incorporating both R,R‐ and S,S‐CHDA (cyan). Hydrogen atoms and solvent molecules are omitted for clarity, nitrogen atoms are in dark blue.
