Fig. 3. Scope of decarboxylative thiolation.

Reaction conditions. ^aNHPI ester (0.3 mmol), disulfide (0.2 mmol), Mn (0.6 mmol), in DMA (0.2 M), 100 °C, N₂, 15 h; yields are for isolated products. ^bNHPI ester (0.4 mmol). ^cWithout ligand. ^d1-Br was used. ^e1-I was used.