Fig. 5. Scope of deaminative thiolation.

Reaction conditions: ^aN-alkylpyridinium salts (0.1 mmol), benzenesulfonothioates (0.25 mmol), Mn (0.5 mmol), in DMSO (0.2 M), 70 °C, N₂, 20 h; yields are for isolated products. ^bSulfonothioates (0.3 mmol), 80 °C.