Table 1.
Sample locations | Al | As | Ba | Be | Cd | Cr | Co | Cu | Pb | Mg | Mn | Ni | Sr | Ti | Zn |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Area air concentrations (µg m−3) during 65-min shredding task | |||||||||||||||
Air MDC (µg m−3) | 9.64 | 0.193 | 0.482 | 0.0385 | 0.0385 | 0.482 | 0.0385 | 0.482 | 0.724 | 4.82 | 0.482 | 1.93 | 0.482 | 0.482 | 4.82 |
Production | |||||||||||||||
Table next to shredder (at worker’s head height) | 51.1 | 0.192a | 38.8 | 0.384a | 0.384a | 1.33 | 1.64 | 12.5 | 2.91 | 40.3 | 0.569 | 5.00 | 0.807 | 12.5 | 8.34 |
1.8 m away from shredder | 58.0 | 0.192a | 30.1 | 0.384a | 0.384a | 1.31 | 1.21 | 10.4 | 2.49 | 30.0 | 0.752 | 4.34 | 0.691 | 9.67 | 10.4 |
4.3 m away from shredder outside truck) | 13.0 | 0.195a | 4.52 | 0.3849a | 0.3849a | 1.07 | 0.286 | 3.32 | 2.43 | 27.4 | 0.224a | 1.95 | 0.534 | 2.14 | 5.06 |
GM(GSD) | 34(2) | 0.19(1)a | 17(3) | 0.4(1)a | 0.4(1)a | 1.2(1) | 0.83(3)a | 7.6(2) | 2.6(1) | 32(1) | 0.45(2) | 3.5(2) | 0.67(1) | 6.4(3) | 7.6(1) |
Non-production | |||||||||||||||
Generator compartment between trailer and front cabin | 14.9 | 0.192a | 1.57 | 0.384a | 0.384a | 1.14 | 0.0385a | 1.39 | 0.192a | 29.5 | 2.11 | 0.480a | 0.588 | 1.30 | 4.80a |
Surface wipe loadings (µg 100 cm−2) | |||||||||||||||
Surface wipe LOQ (µg sample−1) | 2.50 | 0.0070 | 0.050 | 0.010 | 0.010 | 0.125 | 0.010 | 0.050 | 0.188 | 1.25 | 0.050 | 0.500 | 0.050 | 0.125 | 1.25 |
Production | |||||||||||||||
Top of shredder | 121 000 | 125 | 38 400 | 0.742 | 4.45 | 271 | 1020 | 14 500 | 1190 | 3010 | 520 | 12 700 | 175 | 10 800 | 14 100 |
Floor next to shredder & table | 3840 | 0.007b | 1520 | 0.0433 | 1.79 | 26.5 | 105 | 828 | 80.3 | 316 | 50.2 | 424 | 20.8 | 438 | 692 |
Right inside wall of semi-trailer | 314 | 125 | 105 | 0.010b | 0.010b | 3.60 | 12.6 | 47.0 | 6.62 | 30.1 | 3.43 | 29.7 | 1.97 | 30.5 | 137 |
Table next to shredder | 185 | 0.0070b | 87.1 | 0.010b | 0.0904 | 1.97 | 6.79 | 30.9 | 4.72 | 35.5 | 3.56 | 23.1 | 1.49 | 30.6 | 133 |
Table on dock outside of truck | 285 | 0.625 | 99.5 | 0.010b | 0.56 | 2.97 | 5.77 | 36.4 | 7.22 | 78.4 | 13.2 | 19.2 | 2.50 | 32.7 | 196 |
Handles of truck backdoor | 413 | 1.88 | 98.0 | 0.010b | 0.0573 | 10.7 | 27.0 | 37.5 | 8.64 | 96.7 | 12.6 | 43.0 | 2.21 | 20.8 | 138 |
Top of generator | 247 | 0.0070b | 57.5 | 0.010b | 0.01b | 2.79 | 5.71 | 35.3 | 2.91 | 25.0 | 2.26 | 32.1 | 1.55 | 14.0 | 117 |
GM(GSD) | 966(11)c | 0.48(83) | 314(11)c | 0.022(5) | 0.16(11) | 8.9(6)c | 26(7)c | 135(11)c | 18(8)c | 110(5) | 14(7) | 100(11)c | 5.1(6)c | 88(11)c | 343(6) |
Non-production | |||||||||||||||
Dashboard of driver seat | 174 | 0.0070b | 29.9 | 0.010b | 0.0417 | 1.56 | 2.13 | 20.2 | 2.37 | 50.4 | 4.47 | 8.97 | 1.28 | 9.73 | 110 |
Driving steering wheel and clutch | 159 | 0.0070b | 27.7 | 0.010b | 0.142 | 2.25 | 2.69 | 23.5 | 2.68 | 56.9 | 3.58 | 13.7 | 1.6 | 8.42 | 158 |
Dashboard of passenger seat | 167 | 0.0070b | 21.2 | 0.010b | 0.0874 | 1.43 | 1.98 | 15.9 | 2.22 | 47.8 | 4.43 | 7.87 | 1.16 | 6.75 | 97.5 |
Door handle to the generator compartment | 33.2 | 0.0070b | 3.90 | 0.010b | 0.161 | 0.614 | 0.255 | 7.21 | 1.75 | 24.9 | 0.958 | 1.77 | 0.396 | 2.07 | 215 |
Door handle of driver seat | 55.0 | 0.0070b | 6.95 | 0.010b | 0.0253 | 0.661 | 0.331 | 3.50 | 0.866 | 33.7 | 1.52 | 1.43 | 0.454 | 3.06 | 84.2 |
GM(GSD) | 97(2) | 0.007(1)b | 14(2) | 0.01(1)b | 0.073(2) | 1.15(2) | 0.99(3) | 11(2) | 1.8(2) | 41(1) | 2.5(2) | 4.8(3) | 0.84(2) | 5(2) | 125(1) |
Al = aluminum, As = arsenic, Ba = barium, Be = beryllium, Cd = cadmium, Co = cobalt, Cu = copper, GM = geometric mean, GSD = geometric standard deviation, Pb = lead, MDC = minimum detection concentration, Mg = magnesium, Mn = manganese, Ni = nickel, Sr = strontium, Ti = titanium, and Zn = zinc. Bolded numbers represent the highest values per sample media. Note: E-waste sources for the elements measured in the electronics shredded are listed in Supplementary Table S1, available at Annals of Work Exposures and Health online.
aSamples below MDC or the minimum detection concentration. MDC was calculated as the concentration in air from the reporting mass limits provided by the laboratory over the average air volume of all samples (air volume was calculated from the average airflow during sampling multiplied by the duration of the task).
bSamples below LOQ or the limit of quantitation. LOQ was equal to the reporting mass limits provided by the laboratory in units of µg 100 cm−2 because all samples were taken in an area of 100 cm2.
cProduction areas were significantly higher than non-production areas, determined by Wilcoxon signed rank test at α = 0.05.