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. 2020 Sep 25;11:550497. doi: 10.3389/fphar.2020.550497

Table 2.

Phenolic acids isolated from Tetrastigma hemsleyanum Diels & Gilg.

No. Name Formula Molecular Weight [M-H]- or [M+H]+ (m/z) MS/MS fragments (m/z) References
35 Salicylic acid C7H6O3 138 (60), 120 (100), 92 (72) (Liu, 2000)
36 Ethyl gallate C9H10O5 198 198(52), 170 (20),
153 (100), 125(18)
(Liu, 2000)
37 Gallic acid C7H6O5 170 170 (100), 152 (90), 135(22), 125(30), 107(16), 79(28) (Liu, 2000)
38 1-Caffeoylquinic acid C16H18O9 353.0878 (−) 191.0569, 127.0196 (Sun et al., 2013)
39 5-p-Coumaroylquinic acid C16H18O8 337.0929 (−) 191.0565, 163.0425 (Sun et al., 2013)
40 1-p-Coumaroylquinic acid C16H18O8 337.0929 (−) 191.0568 (Sun et al., 2013)
41 Resveratrol C14H12O3 227 (−) (Zeng, 2013)
42 Chlorogenic acid C16H18O9 353. 0874 (−) 191 (Xu et al., 2014a)
43 Neochlorogenic acid C16H18O9 353. 0887 (−) 191 (Xu et al., 2014a)
44 Cryptochlorogenic acid C16H18O9 353. 0883 (−) 191 (Xu et al., 2014a)
45 3,4-Dihydroxybenzoic acid C7H6O4 155.16 (+) (Chen, 2014)
46 4-Hydroxybenzoic acid C7H6O3 139.16 (+) (Chen, 2014)
47 Trans-4-hydroxycinnamic acid C9H8O3 165.15 (+) (Chen, 2014)
48 Oxyresveratrol C14H12O4 243.0651 (−) (Fu et al., 2015)
49 Protocatechualdehyde C7H6O3 137.0237 (−) (Fu et al., 2015)
50 Piceatannol C14H12O4 (Jiang, 2015)
51 Polydatin C20H22O8 (Jiang, 2015)
52 Vanillic acid C8H8O4 168 168 (Ding et al., 2015b)
53 Citric acid C6H8O7 191.0183 (−) 147, 112 (Sun C. et al., 2018)
54 Gallic acid hexoside C13H16O10 331.0643 (−) 169, 125 (Sun C. et al., 2018)
55 Protocatecheuic acid 3-O-β-D-glucoside C13H16O9 315.0523 (−) 153, 152, 109, 108 (Sun C. et al., 2018)
56 Caffeic acid C9H8O4 179.0342 (−) 135 (Sun C. et al., 2018)

“-”: Some relevant information in the literature is incomplete.

(−): [M-H] - (m/z).

(+): [M+H] + (m/z).