Fig. 2. Quantum ground states stabilized by modulations of the kagome lattice.
Structural and magnetic characteristics are tabulated. The second to last row shows the magnetic interactions on the kagome planes of barlowite 1, barlowite 2, and Zn-substituted barlowite. The thickness of the line indicates bond strength as expressed through its Cu–O–Cu bond angle. In barlowite 2, the variation in angle of ±0.8° is quite small, so the differences in magnetic exchange are also likely small. In Zn0.56 and Zn0.95, the kagome motif consists only of equilateral triangles (green); however, in barlowite 2 the kagome motif is expanded due to a mix of equilateral (green) and distorted (red/blue) triangles. On the other hand, barlowite 1 is more distorted, containing only distorted triangles.