Table 3.
SANS Peak Positions and Power Law Fitting of Low-Q Region for Pristine Nafion and Nafion Nanocomposite Membranes Containing SiNPs at wNP = 5%
| functionalization | crystalline |
ionomer |
low Q |
||
|---|---|---|---|---|---|
| peak position [Å−1] | d-spacing [nm] | peak position [Å−1] | d-spacing [nm] | power law exponent α | |
| no SiNPs | |||||
| pristine Nafion | 0.0584 | 10.8 | 0.141 | 4.45 | |
| no functionalization | |||||
| UF-SiNP | 0.0517 | 12.2 | 0.141 | 4.45 | 3.27 |
| sulfonic acid | |||||
| AS-SiNP | 0.0504 | 12.5 | 0.141 | 4.45 | 3.32 |
| PS-SiNP | 0.0490 | 12.8 | 0.152 | 4.14 | 4.32 |
| LS-SiNP | 0.0598 | 10.5 | 0.146 | 4.29 | 3.37 |
| amine | |||||
| TA-SiNP | 0.0450 | 14.0 | 0.141 | 4.45 | 3.84 |
| AA-SiNP | 0.0517 | 12.2 | 0.141 | 4.45 | 3.57 |
| PA-SiNP | 0.0490 | 12.8 | 0.141 | 4.45 | |
| LA-SiNP | 0.0450 | 14.0 | 0.141 | 4.45 | 4.07 |