|
A
2
|
virial coefficient |
|
b
|
scattering length |
|
c
|
concentration |
|
d
|
tube diamter |
|
D
|
diffusion coefficient |
| GPC |
gel permeation chromatography |
| HPLC |
high pressure liquid chromatography |
|
I(Q) |
scattered intensity |
|
kB
|
Boltzmann constant |
| KWW |
Kohlrausch-Williams-Watts function or stretched exponential |
| LCCC |
liquid chromatography at the chromatographic critical condition |
|
M
|
molecular weight of the polymer |
|
Mc
|
critical molecular weight at which entanglements effects are first observed |
|
Me
|
entanglement molecular weight |
|
Mo
|
molecular weight of polymer repeat unit |
|
M
w
|
weight average molecular weight |
|
M
z
|
z-average molecular weight |
|
msd
|
mean-square displacement |
| NA
|
Avogadro’s number |
| Ni
|
degree of polymerisation of polymer i |
| nn
|
number average number of bonds |
| NMR |
nuclear magnetic resonance |
| NSE |
neutron spin echo |
| OM |
Optical microscopy |
| PB |
poly(butadiene) |
| PDMS |
poly(dimethyl siloxane) |
| PEO |
poly(ethylene oxide) |
| PS |
poly(styrene) |
|
P(Q) |
form factor |
|
Q
|
scattering vector or momentum transfer |
| QENS |
quasielastic neutron scattering |
|
Rg
|
radius of gyration |
|
Rz
|
z-average radius of gyration |
|
Rw
|
weight-average radius of gyration |
| <r2cm(t)> |
centre of mass mean square displacement |
| SANS |
small angle neutron scattering |
| SLD |
neutron scattering length density |
|
S(Q) |
structure factor |
|
S(Q,t) |
intermediate scattering law |
|
S(Q,ω) |
dynamic structure factor |
|
T
|
temperature |
|
Ts
|
spinodal point |
|
Z
|
number of entanglements |
| β |
stretched exponent |
|
χ
|
segment-segment interaction parameter |
| φI
|
volume fraction of polymer i |
| η |
melt viscosity |
|
ηs
|
solvent viscosity |
| ηo
|
zero-shear rate viscosity |
| λ |
wavelength |
|
ν
|
Flory exponent |
|
νi
|
volume of repeat unit |
|
νo
|
reference volume |
| θ |
scattering angle |
|
|
density |
| σ |
spring length of the Rouse model |
|
τ
|
characteristic time |
| τe
|
Rouse relaxation time at the entanglement length Ne
|
| τeff
|
effective time |
| τR
|
Rouse relaxation time |
| τrep
|
reptation time |
| ω |
frequency |
| Ω |
inverse correlation time |
| ξ |
correlation length |
| (Δρ)2
|
neutron contrast factor |