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. 2020 Sep 12;9(9):1193. doi: 10.3390/plants9091193

Table 1.

Identification of the phenolic compounds from the flavonoid class (flavanols, flavonols, and anthocyanins) and hydroxycinnamic acids class in the leaf extracts of the blueberry varieties.

Peak
No.
Retention
Time
Rt (min)
UV
λmax
(nm)
[M + H] +
(m/z)
Compound Subclass
1 2.97 279 307, 290 Gallocatechin Flavanol
2 11.33 280 579, 291 Procyanidin dimer I Flavanol
3 12.01 281, 329 355, 163 5-Caffeoylquinic acid (Chlorogenic acid) Hydroxycinnamic acid
4 12.58 280 291 Catechin Flavanol
5 13.11 280 291 Epicatechin Flavanol
6 13.41 282, 329 181, 163 Caffeic acid Hydroxycinnamic acid
7 13.89 280 865, 291 Procyanidin trimer Flavanol
8 14.79 283, 330 369 Feruloylquinic acid I Hydroxycinnamic acid
9 15.35 263, 355 611, 303 Quercetin-rutinoside (Rutin) Flavonol
10 16.20 263, 355 465, 303 Quercetin-glucoside Flavonol
11 17.83 263, 356 493, 303 Quercetin-acetyl-rhamnoside Flavonol
12 18.69 262, 355 435, 303 Quercetin-arabinoside Flavonol
13 19.74 280 579, 291 Procyanidin dimer II Flavanol
14 20.08 282, 329 517, 163 Dicaffeoylquinic acid Hydroxycinnamic acid
15 21.15 263, 355 628, 303 Quercetin-diglucoside Flavonol
16 21.88 261, 355 303 Quercetin Flavonol
17 11.02 210, 517 449, 287 Cyanidin-glucoside Anthocyanins
18 11.78 214, 517 419, 287 Cyanidin-arabinoside Anthocyanins
19 14.28 218, 518 491, 287 Cyanidin-acetyl-glucoside Anthocyanins