Table 1.

Thermal properties of isopentyl caffeate (ICaf), β-cyclodextrin (β-CD), and inclusion complex (ICaf:β-CD) prepared by physical mixture (PM), kneading (KN), co-evaporation (CO) using molar ratios of (A) 0.25:1, (B) 1:1 and (C) 2:1.

Sample	Events	Tonset (°C)	Tendset (°C)	∆H (J)
β-CD	1	63.80	142.16	1.73
	2	308.71	343.18	1.53
ICaf	1	127.63	133.77	0.22
PM 0.25:1	1	61.92	118.56	0.26
	2	128.80	133.67	0.01
	3	220.79	228.54	0.02
	4	302.49	328.33	0.89
KN 0.25:1	1	96.04	106.75	0.32
	2	298.69	326.48	1.10
CO 0.25:1	1	72.01	124.52	0.71
	2	223.29	230.85	0.02
	3	292.41	327.90	1.56
PM 1:1	1	64.30	103.73	0.76
	2	127.67	134.52	0.05
	3	319.40	332.30	0.51
KN 1:1	1	43.22	93.39	0.58
	2	130.14	133.54	0.01
	3	309.49	320.60	0.48
CO 1:1	1	129.19	132.79	0.01
	2	318.53	320.40	0.51
PM 2:1	1	128.11	132.68	0.09
	2	313.51	325.19	0.27
KN 2:1	1	130.08	133.17	0.04
	2	311.19	326.05	0.38
CO 2:1	1	126.87	133.22	0.04
	2	291.04	322.76	0.64