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Synthetic applications.
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Alkyl bromide (0.1 mmol, 0.033 M), Pd(PPh3)4 (5 mol%), KHCO2 (2 equiv), and benzene (3 mL) under 40 W blue LED irradiation without fan cooling (50 ± 5 °C). All yields are isolated yields.
aPd(PPh3)4 (10 mol%).
b48 h.
cPd(PPh3)4 (2.5 mol%).
