Skip to main content
. Author manuscript; available in PMC: 2021 Oct 14.
Published in final edited form as: Chem Rev. 2020 Apr 23;120(19):10695–10743. doi: 10.1021/acs.chemrev.9b00810

Table 1.

Photoinhibitors and Photoabsorbers

type description absorption wavelength cytocompatibility ref
Photoinhibitors
2,2,6,6-tetramethylpiperidin-l-yl)oxyl (TEMPO)
  • stable free radical

  • adds to end of growing polymer chain and quenches reaction

  • soluble in aqueous media and organic solvents

N/A cytotoxic 92
butyl nitrite
  • alkyl nitrite prepared from n-butanol

  • UV activation induces photolysis of butyl nitrite to generate nitric oxide that terminates chain propagation

moderate absorbance at near-UV with weak absorbance in the blue region cytotoxic 87
tetraethylthiuram disulfide (TETD)
  • chain transfer reaction with propagating radical species reduces polymerization rates

moderate absorbance at near-UV with weak absorbance in the blue region cytotoxic 85,86,101,102
bis [2-(o-chlorophenyl)-4,5-diphenyl imidazole] (o-Cl-HABI)
  • activation of lophyl radicals generated upon HABI photolysis terminates chain propagation

moderate absorbance at near-UV with weak absorbance in the blue region N/A 89
Photoabsorbers
tartrazine
  • yellow food coloring also known as FD&C yellow 5, E102

  • water-soluble

strong absorbance in the near-UV to blue visible light cytocompatible 93,94
curcumin
  • lipophilic

  • derived from turmeric

strong absorbance in the near-UV to blue visible light cytotoxic 9496
anthocyanin
  • derived from blueberries

  • water-soluble

strong absorbance in the blue to yellow visible light range cytotoxic 94,97,103
inorganic gold nanoparticles
  • diameters between 12 and 41 nm

strong absorbance from blue to green visible light region cytocompatible 100
2-hydroxy-4-methoxy-benzophenone-5-sulfonic acid (HMBS)
  • common FDA approved chemical with UV light absorbing properties in sunscreen and cosmetics

UV cytotoxic 92
reactive orange 16 (ROl6) (disodium(3Z)-6-acetamido-4-oxo-3-[[4-(2-sulfonatooxyethylsulfonyl) phenyl]hydrazinylidene] naphthalene-2-sulfonate)
  • anionic azo dye

  • water-soluble

strong absorbance in the UV and from blue to green visible light region N/A 98,99