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. Author manuscript; available in PMC: 2021 Oct 14.
Published in final edited form as: J Am Chem Soc. 2020 Sep 30;142(41):17413–17424. doi: 10.1021/jacs.0c06312

Figure 1.

Figure 1.

A: Representative examples of substrate controlled, biomimetic total syntheses of dimeric diketopiperazine natural products. B: Current work describing the molecular basis for catalyst-controlled NzeB mediated assembly of isomeric dimers.