Catalytic asymmetric synthesis of esters of chiral dialkyl carbinols: Scope. All data are the average of two experiments. Unless otherwise noted, couplings were conducted on a 0.8-mmol scale. a In place of the standard conditions, 2.0 equivalents of (EtO)3SiH and 2.0 equivalents of K3PO4•H2O were used, with i-Pr2O as the solvent. b In place of the standard conditions, a balloonful of propylene was used. c In place of the standard conditions, 5.0 equiv of 1-butene (b.p. 21 °C) was used. d In place of the standard conditions, 2.0 equiv of the olefin was used.