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. 2020 Oct 22;68:104321. doi: 10.1016/j.jlp.2020.104321

Table 3.

HAZOP table based on (CCPS, 2001).

Pos. Deviation Causes Identified Consequence Identified Safeguard/Recommendations Identified
0
High level
Flow from tank truck not discontinued before tank capacity has been reached
Yes
High pressure
Indirect
Level indication with high-level alarm (audible in the control room)
Yes
Inventory control error – truck arrives before needed
Yes
Hexane unloading procedures with a checklist that includes checking field reading of tank before unloading
Other
1
Low level
Inventory control error – truck arrives too late
Yes
No safety consequences – potential process interruption if not refilled before the downstream feed tank is empty
Yes

Other
Low flow or no flow – line from the tank truck to hexane storage tank T-301 through hexane unloading pump
Yes
2
High temperature
No credible causes identified
Other

Other

Other
3
Low temperature
Low ambient temperature while there is water contamination in the tank
Indirect
Possible freezing of accumulated water in the heel of the tank or the tank's drain line or instrument lines, resulting in fracture of the drain line and loss of containment
Indirect

Other
4
High pressure
High level
Other
Release of hexane through the relief valve into the tank's dike
Yes

Other
Fire hazard affecting a large area if not contained by the dike
Yes
Loss of containment (if the overpressure cause exceeds the tank pressure rating)
Yes
5
Low pressure
Tank blocked in before cooldown, following steam-out
Yes
Equipment damage resulting in a collapse of the tank under a vacuum
Yes
Standard procedures for steam-out of vessels
Other
6
High concentration of contaminants (Other than composition)
Water not completely drained following a steam-out or washout
Yes
Possible freezing of accumulated water in the tank during a period of low ambient temperature
Yes

Other
High concentration of contaminants – line from the tank truck to hexane storage tank T-301 through hexane unloading pump
Yes
7 Loss of containment (Elsewhere flow) Corrosion
Partially Release of hexane
Yes
Operation/maintenance response as required, including isolation if needed
No
Erosion
External fire
Capability to manually isolate the tank
No
External impact
Gasket, packing or seal failure
Periodic non-destructive inspection per API recommended practice and ASME code
Yes
Improper maintenance
Instrument or instrument line failure
Fire hazard affecting a large area particularly if the capacity of the dike is exceeded Yes Relief valve that discharges to the tank's dike
Yes
Material defect
Sample station valve leaking
Dike sized for 1.5 times the capacity of the tank
Yes
Vent or drain valve leaking
Low temperature
Emergency response procedures No
High pressure (if the overpressure cause exceeds the equipment pressure rating)