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. 2020 Mar 19;8(13):5360–5370. doi: 10.1021/acssuschemeng.0c00991

Table 5. FTIR Band Area (in Arbitrary Units) at 1712 and 1576 cm–1a.

Sample A1712 [a.u.] A1576 [a.u.] A1581/A1712 [a.u.] × 102
0%-before 18.24 0.038 0.21
0%-after 22.052 0.084 0.38
1%-before 21.47 0.039 0.18
1%-after 19.255 0.066 0.34
2.5%-before 21.253 0.035 0.16
2.5%-after 23.504 0.116 0.49
5%-before 23.87 0.04 0.17
5%-after 23.629 0.173 0.73
7.5%-before 21.123 0.037 0.18
7.5%-after 19.496 0.122 0.63
10%-before 19.921 0.047 0.24
10%-after 18.587 0.177 0.95
a

The 1712 cm–1 is for C=O bond absorption due to the presence of ester, and 1576 cm–1 is for benzene ring absorption of the aromatic ester. The percentage indicates the MCPA-PHBV oligomer concentration in the films.