Table 5. FTIR Band Area (in Arbitrary Units) at 1712 and 1576 cm–1a.
Sample | A1712 [a.u.] | A1576 [a.u.] | A1581/A1712 [a.u.] × 102 |
---|---|---|---|
0%-before | 18.24 | 0.038 | 0.21 |
0%-after | 22.052 | 0.084 | 0.38 |
1%-before | 21.47 | 0.039 | 0.18 |
1%-after | 19.255 | 0.066 | 0.34 |
2.5%-before | 21.253 | 0.035 | 0.16 |
2.5%-after | 23.504 | 0.116 | 0.49 |
5%-before | 23.87 | 0.04 | 0.17 |
5%-after | 23.629 | 0.173 | 0.73 |
7.5%-before | 21.123 | 0.037 | 0.18 |
7.5%-after | 19.496 | 0.122 | 0.63 |
10%-before | 19.921 | 0.047 | 0.24 |
10%-after | 18.587 | 0.177 | 0.95 |
The 1712 cm–1 is for C=O bond absorption due to the presence of ester, and 1576 cm–1 is for benzene ring absorption of the aromatic ester. The percentage indicates the MCPA-PHBV oligomer concentration in the films.