Table 6. Structural Parameters (Å and Degrees) in (H3N)3···ZF3 at the MP2/aug-cc-pVDZ Level of Theory.
r(N···Z) | R(Z–F) | Φ(N···Z–F) | Σ(F–Z–F) | ΔΣ(F–Z–F) | |
---|---|---|---|---|---|
(NH3)3···PF3 | 2.959 | 1.657 | 163.5 | 282.0 | –9.2 |
2.954 | 1.656 | 163.4 | |||
2.949 | 1.656 | 163.2 | |||
(NH3)3···AsF3 | 2.822 | 1.786 | 159.6 | 275.1 | –13.1 |
2.820 | 1.786 | 159.6 | |||
2.820 | 1.785 | 159.5 | |||
(NH3)3···SbF3 | 2.789 | 1.970 | 150.8 | 266.5 | –18.0 |
2.789 | 1.970 | 150.7 | |||
2.788 | 1.970 | 150.7 | |||
(NH3)3···BiF3 | 2.769 | 2.081 | 150.9 | 268.3 | –18.3 |
2.769 | 2.081 | 150.9 | |||
2.769 | 2.081 | 150.9 |