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. 2020 Jun 10;124(27):5654–5664. doi: 10.1021/acs.jpcb.0c02635

Figure 9.

Figure 9

Water-content influence on the quantum yield of the radical-pair [BP···Q+] formed via the ET mechanism of 3BP quenching by anisole in microheterogeneous ACN–H2O (solid line) and the fraction Pesc of pairs escaping into free ions (dashed line), anticipated from the experimental free-radical-ion quantum yield ΦP presented in Figure 4 (see text). The vertical line delimits two regions: VACN > Vw (left) and Vw > VACN (right).