Table 1. Electrodeposition of 225Aca.
activity
in electrolyte |
activity on electrode |
||||
---|---|---|---|---|---|
events | time (min) | mCi | % | mCi | % |
start of electroplating | 0 | 1.34 | 100 | ||
end of electroplating | 98 | 0.228 | 17.0 | 1.07 | 80.2 |
measurement of activities on the electrode as a function of time after the end of electroplating | 2 | 0.677 | 63.0 | ||
7 | 0.775 | 72.2 | |||
18 | 0.836 | 77.8 | |||
41 | 0.982 | 91.4 | |||
56 | 1.05 | 97.8 | |||
62 | 1.07 | 100 |
The electrolyte (10 mL of 0.01 M HNO3) was magnetically stirred during the electrodeposition. Both working and counter electrodes were Pt (see the Preparation of 225Ac Source section for details). Electrodeposition was conducted under a constant dc potential of 10–11 V. In this experiment, gross radioactivity was measured in an ionization chamber (see the Chemicals, Radioisotopes, and Radioactivity Measurement section).