Table 3.
Name, abbreviation, and structure of polymers used in this study.
| Name | Abbreviation | Structure | Substituent/AHG |
|---|---|---|---|
| Hydroxypropyl methyl cellulose acetate succinate (MF grade) | HPMCAS |
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|
|
| Hydroxypropyl methyl cellulose (E3 grade) | HPMC |
|
|
| Poly(vinylpyrrolidone) vinyl acetate VA 64 | PVPVA |
|
|
| Poly(vinylpyrrolidone) K 29/32 | PVP |
|
|
| Cellulose acetate phthalate | CA Ph |
|
|
| Hydroxypropyl cellulose | HPC |
|
|
| 5-Carboxypent-1-yl hydroxypropyl cellulose26 | CPHPC-106 |
|
DS(HP): 2.20 MS(HP): 4.40 DS(CP): 1.06 |
| 5-Carboxypent-1-yl hydroxypropyl cellulose26 | CPHPC-282 |
|
DS(HP): 2.20 MS(HP): 4.40 DS(CP): 2.82 |
| 5-Carboxyprop-1-yl hydroxypropyl cellulose26 | CPHPC-069 |
|
DS(HP): 2.2 MS(HP): 4.4 DS(CPr): 0.69 |
| Cellulose backbone structure |
|
||
| Cellulose propionate trioxodecanoate11 | CPTod-202 |
|
DS(Pr): 0.98 DS(TOD): 2.02 |
| Cellulose acetate adipate poly(ethylene glycol) ester11 | CAAd PEG |
|
DS(Ac): 1.82 DS(Ad): 0.56 |
| Cellulose acetate adipate hydroxyethyl ester11 | CAAd HOEt |
|
DS(Ac): 1.82 DS(Ad): 0.56 |
| Cellulose acetate adipate propionate37 | CAAdP 0.85 |
|
DS(Ac): 0.04 DS(Pr): 2.09 DS(Ad): 0.85 |
| Cellulose acetate adipate37 | CAAd 0.67 |
|
DS(Ac): 1.82 DS(Ad): 0.67 |
| Cellulose acetate suberate37 | CA Sub |
|
DS(Ac): 1.82 DS(Sub): 0.90 |
| Cellulose acetate 3-(2-carboxyethylthio)-adipate, hydroxyethyl ester11 | CAAd 3CES HE |
|
DS(Ac): 1.82 DS(Ad): 0.79 |
| Cellulose acetate 9-(2-carboxyethylthio)-Undecanoate, 2-(trimethylammonio)-ethyl ester11 | CAUn 3CES TAE |
|
DS(Ac): 1.82 DS(Un): 0.67 |
| Methyl cellulose adipate25 | MCAd |
|
DS(Me): 1.62 DS(Ad):1.1 |
| Methyl 5-carboxypentyl cellulose25a | MCCP-A |
|
DS(Me): 1.62 DS(CP): 1.37 |
| Methyl 5-carboxypentyl cellulose25a | MCCP-B |
|
DS(Me): 1.62 DS(CP): 1.37 |
| Ethyl cellulose backbone |
|
||
| Ethyl 5-carboxypentyl cellulose25a | ECCP-A | Starting source commercial ethyl cellulose |
DS(Et): 2.58 DS(CP): 0.38 |
| Ethyl 5-carboxypentyl cellulose25a | ECCP-B | Starting source commercial ethyl cellulose |
DS(Et): 2.58 DS(CP): 0.38 |
| Ethyl 5-carboxypentyl cellulose25b | ECCP-C | Starting source wood pulp |
DS(Et): 2.19 DS(CP): 0.36 |
| Ethyl 5-carboxypentyl cellulose25b | ECCP-D | Starting source commercial methyl cellulose |
DS(Et): 2.2 DS(CP): 0.56 |
Note that all structures above are not meant to imply regioselective substitution; they are depicted this way only for clarity and simplicity.
AHG anhydroglucose unit.
aPolymers differ only in how they are hydrogenated in the final synthetic step.
bPolymers differ in DS (degree of substitution, Et) of starting material and therefore product from those above.
