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. 2020 Sep 23;22(10):1065. doi: 10.3390/e22101065
A area m2
CP molar constant-pressure heat capacity, KJ/(mol·K)
Dp catalyst pellet diameter, m
F molar flow rate, mol/s
Jq heat flux density, W/m2
K equilibrium constant
L length, m
P pressure, bar
R universal gas constant, J/(mol·K)
r reaction rate, mol/(kg·s)
T temperature, K
v flow velocity, m/s
z length, m
Greek letters
ε catalyst bed porosity
η dynamic viscosity, kg/(m·s)
κ rate constant of chemical reaction
νi the stoichiometric number of reaction component i
ρ density, kg·m3
σ local EGR, J/K
Σ total
ΔrG Gibbs free energy change of chemical reaction, J
ΔrH enthalpy change of chemical reaction, J
Subscripts
c cross section of tubular plug-flow reactor
cr chemical reaction
f fluid flow
ht heat transfer
i component
in inlet
j reaction types (I) and (II)
out outlet
p catalyst pellet
q quantity of heat
r reaction
tot total
w wall of tubular plug-flow reactor
Abbreviations
EGR entropy generation rate
FTT finite-time thermodynamics
H-S hybrid-Sulphur thermochemical cycle
NSGA-II second generation non-dominated solution sequencing genetic algorithm
S-I sulphur-Iodine thermochemical cycle