. 2020 Sep 26;9(10):1368. doi: 10.3390/foods9101368

Table 1.

Chromatographic parameters and MS/MS (tandem mass spectrometric) detection for compounds analyzed by LC-MS/MS (liquid chromatography tandem mass spectrometric detection).

Name	RT ¹ (min)	DRT ² (min)	Polarity	Transitions	Collision Energy
2,4-D	9.60	1.5	ESI−	QI ³ 218.9 > 161.	11
				1^st CI ⁴ 218.9 > 124.9	35
				2^nd CI 220.9 > 162.9	11
Acephate	4.56	1.5	ESI+	QI 184.0 > 143.0	5
Acephate	4.56	1.5	ESI+	1^st CI 184.0 > 125.0	15
Acetamiprid	6.56	1.0	ESI+	QI 223.1 > 126.0	15
Acetamiprid	6.56	1.0	ESI+	1^st CI 223.1 > 56.0	15
Aldicarb	8.05	1.5	ESI+	QI 208.1 > 116.2	10
Aldicarb	8.05	1.5	ESI+	1^st CI 208.1 > 89.1	24
Aldicarb-Sulfone	4.99	1.5	ESI+	QI 223.1 > 148.0	5
Aldicarb-Sulfone	4.99	1.5	ESI+	1^st CI 223.1 > 76.0	5
Aldicarb-Sulfoxide	4.88	1.5	ESI+	QI 207.1 > 131.9	0
Aldicarb-Sulfoxide	4.88	1.5	ESI+	1^st CI 207.1 > 89.1	8
Allethrin	19.36	1.5	ESI+	QI 303.2 > 135.0	10
Allethrin	19.36	1.5	ESI+	1^st CI 303.2 > 123	20
Ametryn	13.15	1.5	ESI+	QI 228.1 > 186.1	20
				1^st CI 228.1 > 116.1	28
				2^nd CI 228.1 > 96.0	25
Aminocarb	7.32	1.5	ESI+	QI 209.1 > 152.2	12
Aminocarb	7.32	1.5	ESI+	1^st CI 209.1 > 137.2	20
Atrazine	11.34	1.5	ESI+	QI 216.1 > 174.1	16
Atrazine	11.34	1.5	ESI+	1^st CI 216.1 > 68.0	40
Avermectin B1a	21.71	1.5	ESI+	QI 890.5 > 567.4	8
Avermectin B1a	21.71	1.5	ESI+	1^st CI 890.5 > 305.1	16
Azaconazole	11.03	1.5	ESI+	QI 300.0 > 231.1	16
Azaconazole	11.03	1.5	ESI+	1^st CI 300.0 > 159.0	28
Azinphos-Ethyl	14.74	1.5	ESI+	QI 346.1 > 132.1	12
Azinphos-Ethyl	14.74	1.5	ESI+	1^st CI 346.1 > 97.0	32
Azinphos-Methyl	12.15	1.5	ESI+	QI 318.0 > 261.0	0
Azinphos-Methyl	12.15	1.5	ESI+	1^st CI 318.0 > 132.1	8
Azoxystrobin	12.90	1.5	ESI+	QI 404.1 > 372.1	12
				1^st CI 404.1 > 344.1	28
				2^nd CI 404.1 > 329.1	36
Benalaxyl	16.86	1.5	ESI+	QI 326.2 > 294.1	4
Benalaxyl	16.86	1.5	ESI+	1^st CI 326.2 > 148.1	27
Bitertanol	16.98	1.5	ESI+	QI 338.2 > 99.1	10
Bitertanol	16.98	1.5	ESI+	1^st CI 338.2 > 70.0	4
Boscalid	13.34	1.5	ESI+	QI 343.0 > 307.1	16
Boscalid	13.34	1.5	ESI+	1^st CI 343.0 > 271.2	32
Bromacil	9.29	1.5	ESI+	QI 261.0 > 205.0	20
Bromacil	9.29	1.5	ESI+	1^st CI 261.0 > 187.9	40
Bromuconazole	15.50	3.0	ESI+	QI 378.0 > 159.0	32
Bromuconazole	15.50	3.0	ESI+	1^st CI 378.0 > 70.0	35
Buprofezin	19.13	1.5	ESI+	QI 306.2 > 201.1	5
Buprofezin	19.13	1.5	ESI+	1^st CI 306.2 > 116.1	10
Cadusafos	17.96	1.5	ESI+	QI 271.1 > 130.9	20
Cadusafos	17.96	1.5	ESI+	1^st CI 271.1 > 97.0	40
Carbaryl	9.80	1.5	ESI+	QI 202.1 > 145.1	4
Carbaryl	9.80	1.5	ESI+	1^st CI 202.1 > 127.1	28
Carbendazim	7.07	1.5	ESI+	QI 192.1 > 160.1	16
Carbendazim	7.07	1.5	ESI+	1^st CI 192.1 > 132.1	32
Carbofuran	9.35	1.5	ESI+	QI 222.1 > 165.1	20
Carbofuran	9.35	1.5	ESI+	1^st CI 222.1 > 123.1	30
3-Hydroxycarbofuran	6.35	1.5	ESI+	QI 238.1 > 220.1	0
3-Hydroxycarbofuran	6.35	1.5	ESI+	1^st CI 238.1 > 163.1	8
Carboxin	9.88	1.5	ESI+	QI 236.1 > 143.1	12
Carboxin	9.88	1.5	ESI+	1^st CI 236.1 > 93.1	36
Chlorfenvinphos	17.20	1.5	ESI+	QI 358.9 > 155.0	8
Chlorfenvinphos	17.20	1.5	ESI+	1^st CI 358.9 > 99.2	28
Chlorfluazuron	20.00	1.5	ESI+	QI 539.9 > 383.0	44
Chlorfluazuron	20.00	1.5	ESI+	1^st CI 539.9 > 158.0	36
Chlorpyrifos	20.20	1.5	ESI+	QI 349.9 > 198.0	20
Chlorpyrifos	20.20	1.5	ESI+	1^st CI 349.9 > 97.0	20
Chlorpyrifos-Methyl-Oxon	15.89	1.5	ESI+	QI 334.0 > 306.0	8
Chlorpyrifos-Methyl-Oxon	15.89	1.5	ESI+	1^st CI 334.0 > 278.0	8
Clofentezine	16.99	1.5	ESI+	QI 303.0 > 138.0	12
Clofentezine	16.99	1.5	ESI+	1^st CI 303.0 > 102.0	40
Clomazone	12.70	1.5	ESI+	QI 242.1 > 127.0	20
				1^st CI 240.1 > 125.0	20
				2^nd CI 240.1 > 89.1	56
Clothianidin	6.08	1.5	ESI+	QI 250.0 > 169.0	8
Clothianidin	6.08	1.5	ESI+	1^st CI 250.0 > 131.9	8
Cyanazine	8.43	1.5	ESI+	QI 241.1 > 214.1	18
Cyanazine	8.43	1.5	ESI+	1^st CI 241.1 > 104.0	44
Cyanofenphos	16.60	1.0	ESI+	QI 304.1 > 276.0	12
Cyanofenphos	16.60	1.0	ESI+	1^st CI 304.1 > 157.0	24
Cyazofamid	15.43	1.5	ESI+	QI 325.0 > 261.0	4
Cyazofamid	15.43	1.5	ESI+	1^st CI 325.0 > 108.0	8
Cymoxanil	6.97	1.5	ESI+	QI 199.1 > 128.0	4
Cymoxanil	6.97	1.5	ESI+	1^st CI 199.1 > 110.9	12
Cyproconazole	14.80	2.0	ESI+	QI 292.1 > 125.0	32
Cyproconazole	14.80	2.0	ESI+	1^st CI 292.1 > 70.0	16
Cyprodinil	17.10	1.5	ESI+	QI 226.1 > 108.0	30
Cyprodinil	17.10	1.5	ESI+	1^st CI 226.1 > 93.0	40
Cyromazine	4.48	1.5	ESI+	QI 167.1 > 125.0	16
Cyromazine	4.48	1.5	ESI+	1^st CI 167.1 > 85.0	16
Diafenthiuron	20.82	1.5	ESI+	QI 385.2 > 329.2	16
Diafenthiuron	20.82	1.5	ESI+	1^st CI 385.2 > 278.2	32
Diazinon	17.10	1.5	ESI+	QI 305.1 > 169.1	32
Diazinon	17.10	1.5	ESI+	1^st CI 305.1 > 97.0	40
Dichlorvos	9.11	1.5	ESI+	QI 221.0 > 109.0	12
Dichlorvos	9.11	1.5	ESI+	1^st CI 221.0 > 79.0	24
Dicrotophos	5.83	1.5	ESI+	QI 238.0 > 127.0	12
Dicrotophos	5.83	1.5	ESI+	1^st CI 238.0 > 112.1	8
Difenoconazole	17.80	1.5	ESI+	QI 406.1 > 337.0	18
Difenoconazole	17.80	1.5	ESI+	1^st CI 406.1 > 251.0	28
Diflubenzuron	14.96	1.5	ESI+	QI 311.0 > 158.0	8
Diflubenzuron	14.96	1.5	ESI+	1^st CI 311.0 > 141.0	32
Dimethoate	6.53	1.5	ESI+	QI 230.0 > 198.8	0
Dimethoate	6.53	1.5	ESI+	1^st CI 230.0 > 125.0	16
Dimethomorph	13.80	3.0	ESI+	QI 388.1 > 301.1	20
Dimethomorph	13.80	3.0	ESI+	1^st CI 388.1 > 165.1	32
Diniconazole	18.00	1.5	ESI+	QI 326.1 > 159.0	28
Diniconazole	18.00	1.5	ESI+	1^st CI 326.1 > 70.0	28
Disulfoton	17.69	1.5	ESI+	QI 275.0 > 89.0	12
Disulfoton	17.69	1.5	ESI+	1^st CI 275.0 > 61.0	44
Disulfoton-Sulfone	10.72	1.5	ESI+	QI 307.0 > 125.0	10
Disulfoton-Sulfone	10.72	1.5	ESI+	1^st CI 307.0 > 97.0	30
Disulfoton-Sulfoxide	10.78	1.5	ESI+	QI 291.0 > 185.0	10
Disulfoton-Sulfoxide	10.78	1.5	ESI+	1^st CI 291.0 > 157.0	20
Diuron	11.38	1.5	ESI+	QI 2350. > 72.0	20
				1^st CI 233.0 > 160.0	24
				2^nd CI 233.03 > 72.1	20
Emamectin B1a	20.89	2.0	ESI+	QI 886.5 > 158.0	44
Emamectin B1a	20.89	2.0	ESI+	1^st CI 886.5 > 82.1	64
Emamectin B1b	20.34	2.0	ESI+	QI 872.5 > 158.3	40
Emamectin B1b	20.34	2.0	ESI+	1^st CI 872.5 > 82.3	68
Epoxiconazole	15.21	1.5	ESI+	QI 330.1 > 121.0	16
Epoxiconazole	15.21	1.5	ESI+	1^st CI 330.1 > 101.2	52
Ethion	19.65	1.5	ESI+	QI 385.0 > 199.1	4
Ethion	19.65	1.5	ESI+	1^st CI 385.0 > 142.8	24
Etofenprox	22.82	1.5	ESI+	QI 394.2 > 359.0	5
Etofenprox	22.82	1.5	ESI+	1^st CI 394.2 > 177.0	5
Ethoprophos	15.72	1.5	ESI+	QI 243.1 > 130.9	15
Ethoprophos	15.72	1.5	ESI+	1^st CI 243.1 > 97.0	30
Etrimfos	16.80	1.5	ESI+	QI 293.1 > 265.0	26
Etrimfos	16.80	1.5	ESI+	1^st CI 293.1 > 125.0	28
Famoxadone	16.93	1.5	ESI+	QI 392.1 > 330.9	4
Famoxadone	16.93	1.5	ESI+	1^st CI 392.1 > 238.0	12
Fenamiphos	15.92	1.5	ESI+	QI 304.1 > 234.0	12
Fenamiphos	15.92	1.5	ESI+	1^st CI 304.1 > 217.1	20
Fenbuconazole	15.11	1.5	ESI+	QI 337.1 > 125.1	40
Fenbuconazole	15.11	1.5	ESI+	1^st CI 337.1 > 70.0	33
Fenpyroximate	20.91	1.5	ESI+	QI 422.2 > 366.2	12
Fenpyroximate	20.91	1.5	ESI+	1^st CI 422.2 > 135.0	36
Fenthion	16.86	1.5	ESI+	QI 279.0 > 247.1	8
Fenthion	16.86	1.5	ESI+	1^st CI 279.0 > 169.1	12
Fipronil	15.50	1.5	ESI+	QI 437.0 > 368.0	18
Fipronil	15.50	1.5	ESI+	1^st CI 437.0 > 255.0	26
Flazasulfuron	11.24	1.5	ESI+	QI 408.1 > 182.1	28
Flazasulfuron	11.24	1.5	ESI+	1^st CI 408.1 > 83.0	40
Fluazifop-Butyl	18.80	1.5	ESI+	QI 384.1 > 328.1	12
Fluazifop-Butyl	18.80	1.5	ESI+	1^st CI 384.1 > 282.2	20
Flufenoxuron	19.88	1.5	ESI+	QI 489.1 > 158.0	20
Flufenoxuron	19.88	1.5	ESI+	1^st CI 489.1 > 140.9	56
Fluquinconazole	15.11	1.5	ESI+	QI 376.0 > 349.0	20
Fluquinconazole	15.11	1.5	ESI+	1^st CI 376.0 > 307.1	24
Flutriafol	11.17	1.5	ESI+	QI 302.1 > 122.9	28
Flutriafol	11.17	1.5	ESI+	1^st CI 302.1 > 70.1	16
Furathiocarb	19.30	1.5	ESI+	QI 383.2 > 251.9	8
Furathiocarb	19.30	1.5	ESI+	1^st CI 383.2 > 195.0	16
Heptenophos	11.79	1.5	ESI+	QI 251.0 > 127.0	15
Heptenophos	11.79	1.5	ESI+	1^st CI 251.0 > 125.0	25
Hexaconazole	17.40	1.5	ESI+	QI 314.1 > 159.0	30
Hexaconazole	17.40	1.5	ESI+	1^st CI 314.1 > 70.1	20
Hexythiazox	19.90	1.5	ESI+	QI 353.1 > 227.9	8
Hexythiazox	19.90	1.5	ESI+	1^st CI 353.1 > 168.1	24
Imazalil	14.30	3.0	ESI+	QI 297.1 > 201.0	15
Imazalil	14.30	3.0	ESI+	1^st CI 297.1 > 159.0	20
Imazapyr	5.48	3.0	ESI+	QI 262.1 > 217.1	20
Imazapyr	5.48	3.0	ESI+	1^st CI 262.1 > 131.0	40
Imazethapyr	7.42	1.5	ESI+	QI 290.1 > 245.1	24
Imazethapyr	7.42	1.5	ESI+	1^st CI 290.1 > 177.0	29
Imibenconazole	19.60	1.5	ESI+	QI 411.0 > 171.0	20
Imibenconazole	19.60	1.5	ESI+	1^st CI 411.0 > 125.0	40
Imidacloprid	5.97	1.5	ESI+	QI 258.0 > 210.9	12
				1^st CI 256.0 > 208.9	12
				2^nd CI 256 > 175	12
Indoxacarb	17.88	1.5	ESI+	QI 528.1 > 203.0	45
Indoxacarb	17.88	1.5	ESI+	1^st CI 528.1 > 150.0	20
Iprodione	15.98	1.5	ESI+	QI 330.0 > 287.9	10
Iprodione	15.98	1.5	ESI+	1^st CI 330.0 > 244.9	14
Iprovalicarb	15.20	1.5	ESI+	QI 321.2 > 202.9	5
Iprovalicarb	15.20	1.5	ESI+	1^st CI 321.2 > 119	16
Kresoxim-Methyl	16.50	1.5	ESI+	QI 314.1 > 267.0	0
Kresoxim-Methyl	16.50	1.5	ESI+	1^st CI 314.1 > 222.1	10
Linuron	12.67	1.5	ESI+	QI 249.0 > 160.1	20
Linuron	12.67	1.5	ESI+	1^st CI 249.0 > 133.0	36
Lufenuron	19.03	1.5	ESI+	QI 510.9 > 158.0	20
Lufenuron	19.03	1.5	ESI+	1^st CI 510.9 > 141.0	57
Malaoxon	9.37	1.5	ESI+	QI 315.0 > 127.1	20
Malaoxon	9.37	1.5	ESI+	1^st CI 315.0 > 99.2	4
Malathion	14.30	1.5	ESI+	QI 331.0 > 126.9	5
Malathion	14.30	1.5	ESI+	1^st CI 331.0 > 99.0	10
Metalaxyl	11.93	1.5	ESI+	QI 280.2 > 220.1	10
Metalaxyl	11.93	1.5	ESI+	1^st CI 280.2 > 160.1	20
Metconazole	17.30	1.5	ESI+	QI 320.1 > 125.0	48
Metconazole	17.30	1.5	ESI+	1^st CI 320.1 > 70.1	24
Methamidophos	4.31	1.5	ESI+	QI 142.0 > 125.0	10
Methamidophos	4.31	1.5	ESI+	1^st CI 142.0 > 94.0	10
Methidathion	11.95	1.5	ESI+	QI 302.9 > 145.0	0
Methidathion	11.95	1.5	ESI+	1^st CI 302.9 > 85.1	15
Methiocarb	13.14	1.5	ESI+	QI 226.1 > 169.0	4
Methiocarb	13.14	1.5	ESI+	1^st CI 226.1 > 121.1	12
Methomyl	5.44	1.5	ESI+	QI 163.1 > 106.0	4
Methomyl	5.44	1.5	ESI+	1^st CI 163.1 > 88.0	0
Methoxyfenozide	14.08	1.5	ESI+	QI 369.2 > 313.1	0
Methoxyfenozide	14.08	1.5	ESI+	1^st CI 369.2 > 149.0	10
Metolachlor	16.30	1.5	ESI+	QI 284.1 > 252.1	8
Metolachlor	16.30	1.5	ESI+	1^st CI 284.1 > 176.1	24
Metribuzin	9.38	1.5	ESI+	QI 215.1 > 187.1	15
Metribuzin	9.38	1.5	ESI+	1^st CI 215.1 > 84.0	30
Mevinphos	7.35	3.0	ESI+	QI 225.0 > 193.1	0
Mevinphos	7.35	3.0	ESI+	1^st CI 225.0 > 127.0	12
Monocrotophos	5.52	1.5	ESI+	QI 224.1 > 193.0	0
Monocrotophos	5.52	1.5	ESI+	1^st CI 224.1 > 127.0	10
Myclobutanil	14.00	1.5	ESI+	QI 289.1 > 125.1	32
Myclobutanil	14.00	1.5	ESI+	1^st CI 289.1 > 70.1	16
Naled	11.80	1.5	ESI+	QI 380.7 > 127.0	8
Naled	11.80	1.5	ESI+	1^st CI 380.7 > 109.0	24
Omethoate	4.77	1.5	ESI+	QI 214.0 > 125.0	16
Omethoate	4.77	1.5	ESI+	1^st CI 214.0 > 109.0	24
Oxamyl	5.09	1.5	ESI+	QI 237.1 > 90.0	10
Oxamyl	5.09	1.5	ESI+	1^st CI 237.1 > 72.0	12
Paclobutrazol	13.95	1.2	ESI+	QI 294.1 > 125.2	40
Paclobutrazol	13.95	1.2	ESI+	1^st CI 294.1 > 70.1	20
Paraoxon	10.88	1.5	ESI+	QI 276.1 > 220.0	10
Paraoxon	10.88	1.5	ESI+	1^st CI 276.1 > 94.0	40
Paraoxon-Methyl	8.05	1.5	ESI+	QI 248.0 > 201.9	20
Paraoxon-Methyl	8.05	1.5	ESI+	1^st CI 248.0 > 90.0	25
Parathion	16.40	1.5	ESI+	QI 292.0 > 236.1	8
Parathion	16.40	1.5	ESI+	1^st CI 292.0 > 94.1	40
Penconazole	16.70	1.5	ESI+	QI 284.1 > 159	30
Penconazole	16.70	1.5	ESI+	1^st CI 284.1 > 70.1	15
Pencycuron	18.00	1.5	ESI+	QI 329.1 > 125.1	24
Pencycuron	18.00	1.5	ESI+	1^st CI 329.1 > 89.1	60
Pendimethalin	20.20	1.5	ESI+	QI 282.1 > 212.1	4
Pendimethalin	20.20	1.5	ESI+	1^st CI 282.1 > 194.1	16
Phenthoate	16.20	1.5	ESI+	QI 321.0 > 163.1	8
Phenthoate	16.20	1.5	ESI+	1^st CI 321.0 > 79.1	44
Phorate	17.50	1.5	ESI+	QI 261.0 > 199.0	2
Phorate	17.50	1.5	ESI+	1^st CI 261.0 > 75.1	5
Phosmet	12.80	1.5	ESI+	QI 317.9 > 160.0	8
Phosmet	12.80	1.5	ESI+	1^st CI 317.9 > 133.0	36
Phosphamidon	8.30	1.5	ESI+	QI 300.0 > 174.1	8
Phosphamidon	8.30	1.5	ESI+	1^st CI 300.0 > 127.1	16
Picloram	4.71	1.5	ESI+	QI 243.0 > 196.8	22
				1^st CI 243.0 > 169.8	34
				2^nd CI 241 > 222.8	10
Picoxystrobin	16.03	1.5	ESI+	QI 368.1 > 205.2	4
Picoxystrobin	16.03	1.5	ESI+	1^st CI 368.1 > 145.0	20
Pirimicarb	11.08	1.5	ESI+	QI 239.1 > 182.1	12
Pirimicarb	11.08	1.5	ESI+	1^st CI 239.1 > 72.1	20
Pirimiphos-Ethyl	19.39	1.5	ESI+	QI 334.1 > 198.1	22
Pirimiphos-Ethyl	19.39	1.5	ESI+	1^st CI 334.1 > 182.1	24
Pirimiphos-Methyl	18.00	1.5	ESI+	QI 306.2 > 164.1	20
Pirimiphos-Methyl	18.00	1.5	ESI+	1^st CI 306.2 > 108.1	30
Prochloraz	18.03	1.5	ESI+	QI 376.0 > 308.0	4
Prochloraz	18.03	1.5	ESI+	1^st CI 376.0 > 265.9	12
Profenofos	18.83	1.5	ESI+	QI 374.9 > 347.0	12
Profenofos	18.83	1.5	ESI+	1^st CI 374.9 > 304.9	19
Propamocarb	4.72	1.5	ESI+	QI 189.2 > 144.0	8
Propamocarb	4.72	1.5	ESI+	1^st CI 189.2 > 102.0	12
Propargite	20.26	1.5	ESI+	QI 368.1 > 231.2	0
Propargite	20.26	1.5	ESI+	1^st CI 368.1 > 175.2	8
Propiconazole	17.50	1.5	ESI+	QI 342.1 > 159.0	32
Propiconazole	17.50	1.5	ESI+	1^st CI 342.1 > 69.1	16
Propoxur	9.33	1.5	ESI+	QI 210.11 > 168.1	5
Propoxur	9.33	1.5	ESI+	1^st CI 210.11 > 111.1	8
Pyraclostrobin	17.50	1.5	ESI+	QI 388.11 > 193.8	8
Pyraclostrobin	17.50	1.5	ESI+	1^st CI 388.11 > 163.1	20
Pyrazophos	17.26	1.5	ESI+	QI 374.1 > 222.1	16
Pyrazophos	17.26	1.5	ESI+	1^st CI 374.1 > 194.1	32
Pyridaben	21.90	1.5	ESI+	QI 365.1 > 309.1	4
Pyridaben	21.90	1.5	ESI+	1^st CI 365.1 > 147.2	20
Pyridaphenthion	14.36	1.5	ESI+	QI 341.0 > 205.1	10
Pyridaphenthion	14.36	1.5	ESI+	1^st CI 341.0 > 189.0	20
Pyrimethanil	13.88	1.5	ESI+	QI 200.1 > 106.9	20
Pyrimethanil	13.88	1.5	ESI+	1^st CI 200.1 > 82.0	25
Pyriproxyfen	19.90	1.5	ESI+	QI 322.2 > 227.2	12
				1^st CI 322.2 > 185.0	20
				2^nd CI 322.2 > 96	12
Quinalphos	16.48	1.5	ESI+	QI 299.0 > 163.0	20
Quinalphos	16.48	1.5	ESI+	1^st CI 299.0 > 147.0	20
Quizalofop-Ethyl	19.10	1.5	ESI+	QI 373.0 > 271.2	24
Quizalofop-Ethyl	19.10	1.5	ESI+	1^st CI 373.0 > 255.1	36
Simazine	9.45	1.5	ESI+	QI 202.1 > 132.0	22
Simazine	9.45	1.5	ESI+	1^st CI 202.1 > 124.1	26
Spinosyn A	19.87	2.0	ESI+	QI 732.5 > 142.1	28
Spinosyn A	19.87	2.0	ESI+	1^st CI 732.5 > 98.1	60
Spinosyn D	20.78	2.0	ESI+	QI 746.5 > 142.1	35
Spinosyn D	20.78	2.0	ESI+	1^st CI 746.5 > 98.0	55
Spirodiclofen	21.25	1.5	ESI+	QI 411.1 > 313	8
Spirodiclofen	21.25	1.5	ESI+	1^st CI 411.1 > 71.2	15
Spiromesifen	20.67	1.5	ESI+	QI 371.2 > 273.1	12
Spiromesifen	20.67	1.5	ESI+	1^st CI 371.2 > 255.1	24
Sulfentrazone	9.38	1.5	ESI+	QI 404.0 > 306.9	28
Sulfentrazone	9.38	1.5	ESI+	1^st CI 404.0 > 273.0	40
Tebuconazole	16.80	1.5	ESI+	QI 308.1 > 124.9	47
Tebuconazole	16.80	1.5	ESI+	1^st CI 308.1 > 70.0	40
Tebufenozide	16.08	1.5	ESI+	QI 353.2 > 297.1	4
Tebufenozide	16.08	1.5	ESI+	1^st CI 353.2 > 133.0	20
Teflubenzuron	19.00	1.5	ESI+	QI 381.0 > 158.0	12
Teflubenzuron	19.00	1.5	ESI+	1^st CI 381.0 > 141.0	48
Temephos	18.90	1.5	ESI+	QI 467.0 > 419.0	20
Temephos	18.90	1.5	ESI+	1^st CI 467 > 124.9	44
Terbufos	19.60	1.5	ESI+	QI 289.1 > 233.0	0
Terbufos	19.60	1.5	ESI+	1^st CI 289.1 > 57.1	16
Tetraconazole	15.09	1.5	ESI+	QI 372.0 > 159.0	36
Tetraconazole	15.09	1.5	ESI+	1^st CI 372.0 > 70.0	20
Thiabendazole	8.22	1.5	ESI+	QI 202.0 > 175.0	24
Thiabendazole	8.22	1.5	ESI+	1^st CI 202.0 > 131.0	36
Thiacloprid	7.10	1.5	ESI+	QI 253.0 > 126.0	16
Thiacloprid	7.10	1.5	ESI+	1^st CI 253.0 > 90.0	40
Thiamethoxam	5.42	1.5	ESI+	QI 292.0 > 211.1	8
Thiamethoxam	5.42	1.5	ESI+	1^st CI 292.0 > 181.1	20
Thiobencarb	18.03	1.5	ESI+	QI 258.0 > 125.1	25
Thiobencarb	18.03	1.5	ESI+	1^st CI 258.07 > 100.1	5
Thiodicarb	10.59	1.5	ESI+	QI 355.0 > 108.1	8
Thiodicarb	10.59	1.5	ESI+	1^st CI 355.0 > 88.1	8
Thiophanate-Methyl	8.65	1.5	ESI+	QI 343.0 > 151.0	20
Thiophanate-Methyl	8.65	1.5	ESI+	1^st CI 343.0 > 93.0	56
Tolylfluanid	15.99	1.5	ESI+	QI 346.9 > 238.1	12
Tolylfluanid	15.99	1.5	ESI+	1^st CI 346.9 > 137.0	25
Triadimefon	14.80	1.5	ESI+	QI 294.1 > 197.2	8
Triadimefon	14.80	1.5	ESI+	1^st CI 294.1 > 69.1	16
Triadimenol	14.70	1.5	ESI+	QI 296.1 > 99.1	16
Triadimenol	14.70	1.5	ESI+	1^st CI 296.1 > 70.0	12
Triazophos	14.30	1.5	ESI+	QI 314.1 > 162.1	16
Triazophos	14.30	1.5	ESI+	1^st CI 314.1 > 119.1	36
Trichlorfon	6.55	1.5	ESI+	QI 256.9 > 221.0	4
Trichlorfon	6.55	1.5	ESI+	1^st CI 256.9 > 109.0	12
Trifloxystrobin	18.35	1.5	ESI+	QI 409.1 > 186.0	12
Trifloxystrobin	18.35	1.5	ESI+	1^st CI 409.1 > 145.0	52
Triflumizole	18.50	1.5	ESI+	QI 346.1 > 278.0	4
Triflumizole	18.50	1.5	ESI+	1^st CI 346.1 > 43.1	20
Vamidothion	6.39	1.5	ESI+	QI 288.0 > 146.1	6
Vamidothion	6.39	1.5	ESI+	1^st CI 288.0 > 58.0	44
Zoxamide	16.96	1.5	ESI+	QI 336.0 > 187.0	16
Zoxamide	16.96	1.5	ESI+	1^st CI 336.0 > 159.0	44

¹ RT: retention time. ² DRT: delta retention time. ³ QI: quantification ions. ⁴ CI: confirmation ions.