. 2020 Sep 24;10(10):1363. doi: 10.3390/biom10101363

Table 4.

Composition of crude WS extract and DCM-EtOH fractions.

Compounds in Walnut Shell		Extract *	Fractions DCM-EtOH
Fatty Acids and Alcohols		Extract *	97–3 (1) *	97–3 (2) *	97–3 (3) *	96–4 *	95–5 *
Fatty acids	Acid 9:0	0.25 ± 0.02	-	-	-	-	-
	Acid 18:0	0.04 ^a	-	0.13 ^a	-	0.01 ^a	-
	Acid 18:1	0.15 ^a	-	0.56 ± 0.06	-	-	-
	Acid 18:2	0.51 ± 0.05	-	-	-	-	-
Fatty alcohols	Alcohol 16:0	0.40 ± 0.02	-	-	-	-	-
Terpenes and Terpenoids
	Terpineol	-	-	0.02 ^a	-	-	-
	p-menthane-1,8-diol	0.06 ^a	-	-	-	-	-
Di-and triglycerides
	Diglycerides	0.45 ± 0.04	-	0.06 ^a	-	-	0.01 ^a
	Triglycerides	0.13 ^a	-	-	-	-	0.01 ^a
Resin Acids
Resin acids	Isopimaric acid	0.01^a	-	-	-	-	-
Resin acids	Unidentified RT = 22:03-27:80	0.11 ^a	0.02 ^a	0.02 ^a	0.02 ^a	-	-
Modified resin acids	X-OH-7oxoDHA acid	-	-	0.03 ^a	0.01 ^a	-	-
	Dihydroxy-DHA acid	1.39 ± 0.21	-	-	-	-	-
	9-hydroxystearic acid	0.01 ^a	-	0.01 ^a	-	-	-
	X-hydroxyabietic acid	0.02 ^a	-	-	-	-	-
Steroids
	Sitosterol	0.17 ± 0.03	-	0.59 ± 0.09	-	-	-
	Unidentified RT = 28:04-30.69	-	-	0.05 ^a	-	-	-
Phenolic Compounds
Phenols	Vanillin	-	-	0.07 ^a	-	0.01 ^a	-
	Rhododendrol	0.01 ^a	-	-	-	-	-
	3,4-dihydroxybenzaldehyde	0.01 ^a	-	-	-	-	-
	3-methoxy-4-OH-cinnamaldehyde	0.06 ^a	-	0.05 ^a	-	-	-
	Gallic acid	0.32 ± 0.02	0.01 ^a	-	-	0.01 ^a	-
	Protocatechuic acid	0.13 ^a	-	-	-	-	-
	Tyrosol	0.24 ± 0.01	-	-	-	-	-
	Dihydroconiferyl alcohol	0.28 ± 0.01	-	0.04 ^a	-	-	-
	Syringic acid	0.05 ^a	-	-	0.01 ^a	-	-
	Vanillic acid	0.07 ^a	-	0.01 ^a	0.01 ^a	-	-
	4-hydroxybenzoic acid	0.13 ^a	-	-	-	-	0.01 ^a
Phenolic acid	Sinapyl alcohol	0.24 ± 0.02	-	0.04 ^a	0.01 ^a	-	-
	1-guaiacyl-3-OH-1-propanone	0.03 ^a	-	-	-	-	-
	1-guaiacyl-2-OH-1-ethanone	0.03 ^a	-	0.01 ^a	-	-	-
	1-syringylglycerol	0.04 ^a	-	0.01 ^a	0.03 ^a	0.01 ^a	0.01 ^a
	1-guaiacyl -2,3-diOH-1-propanone	0.04 ^a	-	0.01 ^a	-	0.01 ^a	0.01 ^a
	1-guaiacylglycerol	0.16 ± 0.01	-	-	-	-	-
	1,3-(bis-guaiacyl)-1,2-propandiol	0.09 ^a	-	-	-	-	0.01 ^a
	P-hydroxyphenyl glycerol	0.04 ^a	-	-	-	-	0.01 ^a
	Coniferyl alcohol	0.25 ± 0.03	-	0.03 ^a	0.01 ^a	-	-
Stilbenes and diarylheptanoids	4,4′-diOH-3,3′-dimethoxystilbene	0.01 ^a	-	-	0.02 ^a	0.01 ^a	-
Stilbenes and diarylheptanoids	X-c4h4(oh)3; c5h6(oh)3	0.23 ± 0.02	-	0.02 ^a	0.01^a	0.01 ^a	-
Lignans	Resorcinol	0.10 ± 0.02	-	-	-	-	-
	Olivil	0.01 ^a	-	0.01 ^a	-	-	-
	glucopyranoside2[-4(OH)phe]	0.02 ^a	-	-	-	-	-
	HMR	-	-	-	0.01 ^a	-	-
	Todolactol	0.17 ± 0.03	-	0.01 ^a	0.01 ^a	0.01 ^a	0.01 ^a
Flavonoids
tannins	Ellagic acid	0.04 ^a	-	0.01 ^a-	0.01 ^a	-	-
Flavonoids	Pinobanksin	0.01 ^a	-	-	-	-	-
	Pinocembrin	0.06 ^a	-	-	0.02 ^a	0.01 ^a	-
	(+)-Catechin	0.02 ^a	-	0.02 ^a	-	-	0.01 ^a
	Dihydromyricetin	0.03 ^a	-	-	-	-	-
	Quercetin	0.05 ^a	-	0.03 ^a	-	-	-
	Taxifolin	0.21 ± 0.04	-	-	0.01 ^a	-	-
	Gallocatechin	0.22 ± 0.02	-	-	0.06 ^a	0.02 ^a	-
	3′,4′,5′,3,X-PentaOH-dyhydroflavanol	0.07 ^a	-	-	-	0.01 ^a	0.01 ^a
	Monomethyl gallocatechin	0.02 ^a	-	-	-	-	-
Other Compounds
Sugar derivatives	Monosaccharides	6.84 ± 1.02	-	0.88 ± 0.08	0.01 ^a	0.01 ^a	-
	Sugar acids	1.20 ± 0.09	-	0.06 ^a	-	-	-
	Sugar alcohol	1.17 ± 0.06	-	0.01 ^a	-	-	-
Others	Carboxyl acid	1.12 ± 0.14	-	-	-	-	-
	Alpha-lapachone	0.01 ^a	-	0.02 ^a	-	-	-
	Dehydro-alpha-lapachone	0.07 ^a	-	0.10 ± 0.01	-	-	-
	Hydroquinone- β-d-glucopyranoside	0.06 ^a	-	-	-	-	-
	3-OH-2-methyl-pyran-4-one	0.01 ^a	-	0.01 ^a	0.02 ^a	-	-
	Non-identified	0.13 ± 0.03	-	0.24 ± 0.03	-	-	-

Standard deviation (n = 3); ^a s.d. < 0.01. * mg of extracts per g of shells.