Table 27.
Diterpenes from Stachys spp.
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|---|---|---|---|---|---|
| Name | R1 | R2 | |||
| Stachysolone (177) | H | H | |||
| 7-Monoacetyl-stachysolone (178) | Ac | H | |||
| 13-Monoacetyl-stachysolone (179) | H | Ac | |||
| 7,13-Diacetyl-stachysolone (180) | Ac | Ac | |||
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| Annuanone (181) | Stachylone (182) | Stachone (183) | |||
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| Roseostachenone (184) | Roseostachone (185) | Roseostachenol (186) | |||
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| Roseotetrol (187) | 3α,4α-Epoxyroseostachenol (188) | ||||
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| Stachysperoxide (189) | |||||
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| Stachaegyptin A (190) | Stachaegyptin B (191) | ||||
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| Stachaegyptin C (192) | Stachaegyptin D (193) | ||||
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| Stachaegyptin E (194) | Stachaegyptin F (195) | ||||
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| Stachaegyptin G (196) | Stachaegyptin H (197) | ||||
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|
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| Ribenone R=O (198) Ribenol R=αOH,βH(199) |
13-Epi-sclareol (200) | ||||
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| (+)-6-Deoxyandalusol (201) | 13-Epi-jabugodiol (202) | ||||
| |||||
| (+)-Plumosol (203) | |||||
| |||||
| Name | R | R′ | R1 | R2 | R3 |
| Stachysic acid (204) | COOH | CH3 | H | OAc | H |
| 6β-hydroxy-ent-kaur-16-ene (205) | CH3 | CH3 | H | OH | H |
| 6β,18-dihydroxy-ent-kaur-16-ene (206) | CH2OH | CH3 | H | OH | H |
| Ent-3α-acetoxy-kaur-16-en-19-oic acid (207) | CH3 | COOH | OAc | H | H |
| 3α,19-Dihydroxy-ent-kaur-16-ene (208) | CH3 | CH2OH | OH | H | H |
| Ent-3α-hydroxy-kaur-16-en-19-oic acid (209) | CH3 | COOH | OH | H | H |
| 11a,18-Dihydroxy-ent-kaur-16-ene (210) | CH2OH | CH3 | H | H | OH |
 Horminone (211) | |||||
 Stachyrosane 1 (212) |
 Stachyrosane 2 (213) |
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 Betolide (214) |
 Betonicolide (215) |
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|
Name | R1 | R2 | R3 | |
| Betonicoside A (216) | O-Glc | CH2OH | O-Glc | ||
| Betonicoside B (217) | O-Glc | CH2OH | OH | ||
| Betonicoside C (218) | OH | CH2OH | O-Glc | ||
| Betonicoside D (219) | OH | CH2O-Glc | OH | ||
Glc: Glucose.