Figure 9.

Mean desorption times for chains with ${\mathsf{\epsilon }}_{PW}=0.4$ kJ/mol and varying internal potentials. Legend labels correspond to the parameter definitions in Table 1. FJC: freely-jointed chain, FJC+EV: freely-jointed chain with excluded volume, FRC: freely-rotating chain, FRC+EV: freely-rotating chain with excluded volume, FRC+EV+D: freely-rotating chain with excluded volume and dihedral-like potential. The thick and thin error bars are discussed in the caption to Figure 8.