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. Author manuscript; available in PMC: 2020 Nov 2.
Published in final edited form as: J Am Chem Soc. 2020 Jul 1;142(28):12394–12399. doi: 10.1021/jacs.0c04725

Scheme 1. Enantioselective Si–H Bond Insertion of 4-Nitrophenylphenyl Diazomethane Catalyzed by Chiral Dirhodium Catalystsa.

Scheme 1.

aReaction conditions: Catal/D1/S1 = 0.0002:0.2:0.24 (mmol), 1 mL solution of D1 was dropped into a 2 mL solution of S1 and catalyst at 0 °C, <3 min, isolated yield.