Scheme 2.

Substrate Scope of Palladium-Catalyzed Allylic Alkylationa

^aReactions performed on 0.2 mmol scale unless stated otherwise. ^bYield of isolated product. ^cDetermined by chiral SFC analysis. ^dAbsolute configuration of 2e determined by single crystal X-ray diffraction, all other compounds are assigned by analogy. ^eReaction performed on 0.1 mmol scale. ^fReaction performed on 0.107 mmol scale.