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. Author manuscript; available in PMC: 2021 Nov 23.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 Aug 26;59(48):21304–21359. doi: 10.1002/anie.202003755

Scheme 30.

Scheme 30.

X-ray structures of Zn(II)- and Al(III)-based complexes, the initial stereochemical model, results of DFT studies at the ω-B97XD/Def2-TZVPPTHF(SMD)//ω-B97XD/Def2-SVP level), and key experimental data. LG = leaving group.