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. Author manuscript; available in PMC: 2021 Nov 23.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 Aug 26;59(48):21304–21359. doi: 10.1002/anie.202003755

Scheme 52.

Scheme 52.

ECA of alkenyl–Al compounds to acyclic trisubstituted enones proceeds with the opposite enantioselectivity compared to disubstituted substrates (Scheme 47). See Scheme 61 for mechanistic analysis.