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. Author manuscript; available in PMC: 2021 Nov 23.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 Aug 26;59(48):21304–21359. doi: 10.1002/anie.202003755

Scheme 61.

Scheme 61.

Rationale for high e.r. in ECA of β-alkenyl–Al compounds (see Schemes 47 and 53 for methodology). DFT at the M06L/Def2-TZVPP//M06L/Def2-SVP level. See the Supporting Information for details.