Table 2. Dopant ions and their respective precursors for the synthesis of ZnO nanoparticles by wet chemical methods.
Dopant Element | Dopant Precursors | Doping Level | Solvent | Particles Dimensions | Ref. |
---|---|---|---|---|---|
La | LaCl3·7H2O | 5% mol | H2O a | 123 nm 1 | [116] |
Ce | CeCl3·7H2O | 1% mol | H2O a | 20–30 nm 1 | [171] |
Ce(NO3)2·6H2O | 0.1–5% mol | H2O b | 70–85 nm 1 | [112] | |
Nd | Nd(NO3)3·6H2O | 5% mol | H2O a | 101 nm 1 | [172] |
Sm | Sm(NO3)3 ·6H2O | 1–4% mol | H2O a | 35 nm 1 | [193] |
Eu | EuCl3·6H2O | 5% mol | H2O a | 79 nm 1 | [150] |
Eu(NO3)3·5H2O | 5% mol | CH3OH a | 9 nm 2 | [164] | |
Gd | Gd(NO3)3·6H2O | 5% mol | CH3OH a | 9 nm 2 | |
Gd(CH3CO2)3 | 2–30% mol | CH3CH2OH | 4 nm2,3 | [163] | |
V | NH4VO3 | 1% mol | H2O a | 47 nm 2 | [194] |
Mn | Mn(NO3)2 | 0.5–3% mol | CH3CH2OH | 50–120 nm 2 | [183] |
MnCl2 ·4H2O | 1–5% mol | CH3OH | 100 nm 2 | [126] | |
Fe | Fe(SO4)·7H2O | 3–7% mol | H2O a | 15–35 nm 2 | [195] |
FeCl3 | 1–10% mol | H2O a | 9–15 nm 2 | [162] | |
Fe(NO3)3 | 2–6% mol | H2O a | ~250 nm 4 | [196] | |
Co | Fe(NO3)2 ·6H2O | 1–10% mol | H2O | 25–50 nm 2 | [184] |
CoCl2 | 5–10% mol | H2O a | Various morphologies | [175] | |
Ni | NiCl2·6H2O | 3% mol | CH3CH2OH a | 25–40 nm 1 | [159] |
Cu | CuCl2·2H2O | 0.5–30 at.% | H2O b | ~250 nm 4 | [176] |
Ag | AgNO3 | 5% mol | H2O a | 80 nm × 350 nm 5 | [152] |
Li | Li(CH3CO2)3·2H2O | 3-5 at.% | TREG (C6H14O4) | ~250 nm 4 | [144] |
Mg | Mg(NO3)2·6H2O | 5% mol | H2O a | 62 nm | [166] |
Al | Al(NO3)3·9H2O | 15% mol | H2O a | ~60 nm 1 | [187] |
NaOH as base
NH4OH as base
Rod’s mean diameter.
Spherical particles’ diameters.
TMAH (tetramethylammonium hydroxide) and oleic acid were also added in the synthesis procedure.
The dimensions have been estimated by electron microscopy images.
Nanoplates’ thicknesses and diameters.