Table 2. Doping test for V, Ti, Fe, Na and K and external precision tests by Allende, DTS-1 and Orgueil.
Samples | Interference Contribution (ppm)* | ε53Cr | 2se | ε54Cr | 2se | N/[ref.] |
---|---|---|---|---|---|---|
Cr-V-0% | 0 | 0.00 | 0.00 | –0.01 | 0.02 | 5 |
Cr-V-S14 | 24 | 0.00 | 0.02 | 0.00 | 0.02 | [1] |
Cr-V-0.5% | 269 | 0.00 | 0.03 | 0.04 | 0.02 | 5 |
Cr-V-2.5% | 1438 | –0.06 | 0.02 | –0.07 | 0.03 | 5 |
Cr-V-5% | 2764 | –0.09 | 0.01 | –0.12 | 0.04 | 5 |
Cr-Ti-0% | 0 | –0.01 | 0.02 | 0.02 | 0.03 | 5 |
Cr-Ti-S14 | 1609 | 0.01 | 0.02 | 0.00 | 0.02 | [1] |
Cr-Ti-0.5% | 7590 | 0.01 | 0.05 | 0.03 | 0.05 | 5 |
Cr-Ti-1% | 14,269 | 0.02 | 0.03 | 0.06 | 0.08 | 5 |
Cr-Ti-2% | 27,904 | 0.04 | 0.05 | 0.11 | 0.06 | 5 |
Cr-Fe-0% | 0 | 0.00 | 0.01 | 0.01 | 0.02 | 5 |
Cr-Fe-0.01% | 205 | 0.00 | 0.01 | –0.08 | 0.04 | 5 |
Cr-Fe-S14 | 558 | 0.02 | 0.02 | 0.01 | 0.02 | [1] |
Cr-Fe-0.1% | 2505 | 0.01 | 0.01 | –0.04 | 0.05 | 5 |
Cr-Fe-0.5% | 11,846 | –0.01 | 0.02 | –0.19 | 0.04 | 5 |
Cr-Na-50% | 0.04 | 0.05 | 0.11 | 0.05 | 4 | |
Cr-Na-100% | 0.01 | 0.02 | 0.02 | 0.09 | 4 | |
Cr-K-50% | 0.03 | 0.05 | 0.04 | 0.02 | 4 | |
Cr-K-100% | 0.01 | 0.02 | 0.01 | 0.10 | 4 | |
Allende-1 | 0.08 | 0.01 | 0.87 | 0.08 | 5 | |
Allende-2 | 0.10 | 0.02 | 0.90 | 0.02 | 5 | |
Allende-3 | 0.11 | 0.02 | 0.94 | 0.02 | 5 | |
Allende-4 | 0.14 | 0.03 | 0.95 | 0.08 | 5 | |
Allende-5 | 0.10 | 0.02 | 0.96 | 0.05 | 5 | |
Average | 0.10 | 0.04 | 0.92 | 0.07 | 2SD | |
DTS-1-1 | 0.05 | 0.01 | 0.11 | 0.07 | 5 | |
DTS-1-2 | 0.05 | 0.01 | 0.16 | 0.05 | 5 | |
DTS-1-3 | 0.06 | 0.03 | 0.18 | 0.07 | 5 | |
DTS-1-4 | 0.04 | 0.03 | 0.15 | 0.03 | 5 | |
DTS-1-5 | 0.07 | 0.02 | 0.19 | 0.07 | 5 | |
Average | 0.05 | 0.03 | 0.16 | 0.06 | 2SD | |
Orgueil-1 | 0.19 | 0.05 | 1.51 | 0.05 | 5 | |
Orgueil-2 | 0.19 | 0.01 | 1.50 | 0.08 | 5 | |
Average | 0.19 | 0.00 | 1.50 | 0.01 | 2SD |
Note: The references [1] Schiller et al. (2014). The doped samples are the corresponding SCP elemental standards of ICP-MS.
The corresponding V, Ti and Fe interference is for 50Cr, 50Cr and 54Cr respectively.