Table 3. Sample list of the measured transition frequencies for the ground-state of cyanoacetic acid.
| Technique | J′ | Ka′ | Kc′ | F′ | J″ | Ka″ | Kc″ | F″ | Uobs a(MHz) | Ucalc b (MHz) | Uobs-Ucalc c (MHz) |
|---|---|---|---|---|---|---|---|---|---|---|---|
| 2 | 1 | 2 | 2 | 1 | 1 | 1 | 1 | 7898.1967 | 7898.1967 | 0.0001 | |
| 2 | 1 | 2 | 2 | 1 | 1 | 1 | 2 | 7898.5439 | 7898.5424 | 0.0015 | |
| 2 | 1 | 2 | 3 | 1 | 1 | 1 | 2 | 7899.2045 | 7899.2039 | 0.0006 | |
| MB-FTMW | 2 | 1 | 2 | 1 | 1 | 1 | 1 | 2 | 7899.5725 | 7899.5717 | 0.0007 |
| 2 | 1 | 2 | 1 | 1 | 1 | 1 | 0 | 7900.0909 | 7900.0901 | 0.0008 | |
| 3 | 1 | 2 | 3 | 2 | 1 | 1 | 2 | 13009.1663 | 13009.1648 | 0.0015 | |
| 3 | 1 | 2 | 4 | 2 | 1 | 1 | 3 | 13009.4489 | 13009.4480 | 0.0009 | |
| 3 | 1 | 2 | 2 | 2 | 1 | 1 | 1 | 13009.4668 | 13009.4709 | -0.0041 | |
| 2 | 1 | 2 | 1 | 1 | 0 | 1 | 0 | 15821.9328 | 15821.9533 | -0.0205 | |
| 2 | 1 | 2 | 2 | 1 | 0 | 1 | 2 | 15822.3606 | 15822.3688 | -0.0081 | |
| CP-FTMW | 2 | 1 | 2 | 3 | 1 | 0 | 1 | 2 | 15823.0169 | 15823.0303 | 0.0133 |
| 2 | 1 | 2 | 2 | 1 | 0 | 1 | 1 | 15823.3103 | 15823.3319 | -0.0216 | |
| 2 | 1 | 2 | 1 | 1 | 0 | 1 | 1 | 15824.3454 | 15824.3613 | -0.0159 | |
| 5 | 1 | 5 | 5 | 4 | 0 | 4 | 4 | 26032.0800 | 26032.0715 | 0.0085 | |
| 5 | 1 | 5 | 6 | 4 | 0 | 4 | 5 | 26032.1200 | 26032.1139 | 0.0061 | |
| DR-MB-FTMW | 2 | 2 | 0 | 1 | 1 | 1 | 1 | 0 | 32854.6280 | 32854.6368 | -0.0088 |
| 2 | 2 | 0 | 3 | 1 | 1 | 1 | 2 | 32854.6940 | 32854.6951 | 0.0011 | |
| 2 | 2 | 0 | 2 | 1 | 1 | 1 | 1 | 32854.7600 | 32863.7728 | 0.0138 |
Notes. Upper and lower state quantum numbers are indicated by’ and”, respectively.
Observed frequency.
Calculated frequency.
Observed minus calculated frequency.