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. Author manuscript; available in PMC: 2022 Nov 3.
Published in final edited form as: Phys Chem Chem Phys. 2011 Mar 9;13(15):6955–6969. doi: 10.1039/c0cp02487b

Table 7. Contributions to the dielectric constant, resolved by species: self- and cross-terms.

xH2O = 1.0, εdiag + 1 =, ε = 108.8
5ZNF H2O CF3SO3 EMIM+
5ZNF 4.4 2.2 0.0 0.0
H2O 2.2 98.7 0.1 0.0
CF3SO3 0.0 0.1 0.1 0.0
EMIM+ 0.0 0.0 0.0 0
xH2O = 0.927, εdiag + 1 =, ε = 72.8
5ZNF H2O CF3SO3 EMIM+
5ZNF 24.1 1.0 0.0 0.0
H2O 1.0 29.2 1.9 0.1
CF3SO3 0.0 1.9 3.8 0.1
EMIM+ 0.0 0.1 0.1 0.5
xH2O = 0.854, εdiag + 1 =, ε = 41.7
5ZNF H2O CF3SO3 EMIM+
5ZNF 19.7 0.5 -0.1 -0.3
H2O 0.5 12.9 1.9 0.1
CF3SO3 -0.1 1.9 4.3 0.1
EMIM+ -0.3 0.1 0.1 0.7
xH2O = 0.751, εdiag + 1 =, ε = 39.1
5ZNF H2O CF3SO3 EMIM+
5ZNF 24.0 0.2 -0.5 -0.3
H2O 0.2 7.2 1.0 -0.1
CF3SO3 -0.5 1.0 4.8 0.2
EMIM+ -0.3 -0.1 0.2 1.0
xH2O = 0.675, εdiag + 1 =, ε = 30.5
5ZNF H2O CF3SO3 EMIM+
5ZNF 16.6 -0.1 0.1 0.1
H2O -0.1 4.7 1.0 0.0
CF3SO3 0.1 1.0 4.9 0.2
EMIM+ 0.1 0.0 0.2 0.9