Table 1. NMR Chemical Shifts and Temperature Coefficients of Different Protons in CCSHR.
residues | chemical shifts (ppm) | dδ/dT (ppb/°C) | ||||
---|---|---|---|---|---|---|
NH | CαH | CβH | CγH | CδH | ||
Phe1 | 4.21 | 3.21 | ||||
Aib2 | 8.61 | 1.35 | 1.09 | −9.6 | ||
Leu3 | 7.89 | 4.36 | 1.69 | 1.59 | 0.89 | −10.6 |
Glu4 | 7.97 | 4.18 | 2.02 | 2.48 | −4.3 | |
Aib5 | 8.29 | 1.41 | −9.4 | |||
Leu6 | 7.59 | 4.24 | 1.48 | 1.40 | 0.84 | −3.4 |
Phe7 | 8.08 | 4.67 | 3.07/3.25 | −6.6 | ||