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. Author manuscript; available in PMC: 2020 Nov 4.
Published in final edited form as: ChemSusChem. 2019 Jun 5;12(13):3003–3007. doi: 10.1002/cssc.201900727

Table 1.

Optimization of Pd0-catalyzed aerobic allylic acyloxylation.

graphic file with name nihms-1637707-t0009.jpg
Entry %[DAF/Pd][a] 1a
[M]		 BzOH
[eq]		 %Me2BQ %Fe(Pc) %
Yield[b]
1 2.5 1.08 3 ---- ---- 24
2 2.5 1.08 3 5 ---- 56
3 2.5 1.08 3 5 2.5 72
4 2.5 1.08 3 5 0.5 78
5 2.5 1.08 3 1.25 0.5 51
6 5 1.08 2 10 0.5 98
7 5 1.08 1.2 10 0.5 93
8[c] 5 1.08 1.2 10 0.5 4
[a]

[DAF/Pd] = 2:1 DAF:Pd2(dba)3 Reported mol% DAF and mol% total Pd

[b]

NMR yield relative to 1,3,5-trimethoxybenzene

[c]

No DAF.