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. 2020 Oct 22;33:106454. doi: 10.1016/j.dib.2020.106454

Table 8.

Tris(4,4′-dimethoxy-2,2′bipyridine)osmium bis(tetrafluoroborate), 8, electrochemical data (potential in V vs. FcH/FcH+) of the OsII/III redox couple in acetonitrile (CH3CN) for ca 0.005 mol.dm−3 complex solution at the indicated scan rates.

Scan Rate (V/s) Epa
(V)
106 Ipa
(A)
Epc
(V)
106Ipc
(A)
E°’
(V)
ΔE
(V)
Ipc/Ipa
0.05 0.113 2.10 0.036 2.14 0.074 0.077 0.98
0.15 0.114 3.70 0.035 3.77 0.074 0.079 0.98
0.20 0.112 4.26 0.036 4.37 0.074 0.076 0.98
0.25 0.110 4.79 0.039 4.90 0.074 0.071 0.98
0.30 0.110 5.43 0.039 5.54 0.074 0.071 0.98
0.50 0.113 6.94 0.036 7.09 0.074 0.077 0.98
1.00 0.113 10.57 0.035 10.79 0.074 0.078 0.98
5.00 0.121 19.98 0.027 20.32 0.074 0.094 0.98
10.0 0.132 28.20 0.016 28.65 0.074 0.116 0.98