Table 2. Selected Bond Lengths (Å) and Angles (deg) for 3-S and 4-Sa.
|
3-S (M = Rh) |
4-S (M = Ir) |
|||
|---|---|---|---|---|
| molecule 1 | molecule 2 | molecule 1 | molecule 2 | |
| M-S(1) | 2.379(3) | 2.388(3) | 2.373(5) | 2.368(5) |
| M-P(1) | 2.332(3) | 2.330(3) | 2.327(4) | 2.323(5) |
| M-P(2) | 2.397(2) | 2.403(2) | 2.366(4) | 2.376(4) |
| M-Ga̲ | 1.899(6) | 1.912(6) | 1.910(9) | 1.930(10) |
| S(1)-M-P(1) | 85.11(9) | 84.97(9) | 84.77(17) | 84.99(17) |
| S(1)-M-P(2) | 89.67(9) | 89.99(9) | 89.45(16) | 89.68(16) |
| S(1)-M-Ga̲ | 125.97(18) | 125.68(18) | 125.7(3) | 125.8(3) |
| P(1)-M-P(2) | 82.91(9) | 82.91(9) | 82.62(16) | 82.90(16) |
| P(1)-M-Ga̲ | 125.60(18) | 126.14(18) | 125.9(3) | 126.5(3) |
| P(2)-M-Ga̲ | 132.28(18) | 131.95(17) | 132.8(3) | 131.7(3) |
a
G represents the centroid of the Cp* ligand.