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. 2020 Oct 9;76(Pt 11):1741–1747. doi: 10.1107/S2056989020013341
Ni—N1 1.853 (3) C10—H10 0.9500
Ni—N2i 1.8667 (18) C10—C11 1.386 (3)
Ni—N2 1.8666 (18) C11—C12 1.401 (3)
Ni—C22 1.809 (3) C11—C14 1.515 (3)
O—C22 1.126 (4) C12—H12 0.9500
N1—C3i 1.364 (2) C12—C13 1.391 (3)
N1—C3 1.364 (2) C13—H13 0.9500
N2—C4 1.393 (3) C14—H14A 0.9800
N2—C7 1.373 (3) C14—H14B 0.9800
C1—H1 0.9500 C14—H14C 0.9800
C1—C2 1.386 (3) C15—C16 1.402 (3)
C1—C2i 1.386 (3) C15—C20 1.395 (3)
C2—H2 0.9500 C16—H16 0.9500
C2—C3 1.403 (3) C16—C17 1.391 (3)
C3—C4 1.442 (3) C17—H17 0.9500
C4—C5 1.402 (3) C17—C18 1.394 (4)
C5—C6 1.411 (3) C18—C19 1.391 (3)
C5—C8 1.482 (3) C18—C21 1.512 (3)
C6—H6 0.9500 C19—H19 0.9500
C6—C7 1.390 (3) C19—C20 1.392 (3)
C7—C15 1.478 (3) C20—H20 0.9500
C8—C9 1.396 (3) C21—H21A 0.9800
C8—C13 1.398 (3) C21—H21B 0.9800
C9—H9 0.9500 C21—H21C 0.9800
C9—C10 1.390 (3)
N1—Ni—N2 83.20 (6) C11—C10—H10 119.2
N1—Ni—N2i 83.20 (6) C10—C11—C12 117.7 (2)
N2—Ni—N2i 165.18 (11) C10—C11—C14 122.3 (2)
C22—Ni—N1 160.41 (13) C12—C11—C14 119.9 (2)
C22—Ni—N2 97.39 (5) C11—C12—H12 119.6
C22—Ni—N2i 97.40 (6) C13—C12—C11 120.8 (2)
C3i—N1—Ni 117.66 (13) C13—C12—H12 119.6
C3—N1—Ni 117.66 (13) C8—C13—H13 119.4
C3i—N1—C3 124.2 (3) C12—C13—C8 121.2 (2)
C4—N2—Ni 114.70 (15) C12—C13—H13 119.4
C7—N2—Ni 137.48 (15) C11—C14—H14A 109.5
C7—N2—C4 107.19 (18) C11—C14—H14B 109.5
C2—C1—H1 118.9 C11—C14—H14C 109.5
C2i—C1—H1 118.9 H14A—C14—H14B 109.5
C2i—C1—C2 122.2 (3) H14A—C14—H14C 109.5
C1—C2—H2 120.7 H14B—C14—H14C 109.5
C1—C2—C3 118.6 (2) C16—C15—C7 120.5 (2)
C3—C2—H2 120.7 C20—C15—C7 121.4 (2)
N1—C3—C2 118.2 (2) C20—C15—C16 118.1 (2)
N1—C3—C4 110.88 (19) C15—C16—H16 119.7
C2—C3—C4 130.9 (2) C17—C16—C15 120.6 (2)
N2—C4—C3 112.82 (19) C17—C16—H16 119.7
N2—C4—C5 109.72 (19) C16—C17—H17 119.4
C5—C4—C3 137.4 (2) C16—C17—C18 121.2 (2)
C4—C5—C6 105.6 (2) C18—C17—H17 119.4
C4—C5—C8 129.0 (2) C17—C18—C21 121.4 (2)
C6—C5—C8 125.5 (2) C19—C18—C17 118.1 (2)
C5—C6—H6 125.8 C19—C18—C21 120.5 (2)
C7—C6—C5 108.4 (2) C18—C19—H19 119.4
C7—C6—H6 125.8 C18—C19—C20 121.1 (2)
N2—C7—C6 109.10 (19) C20—C19—H19 119.4
N2—C7—C15 122.3 (2) C15—C20—H20 119.6
C6—C7—C15 128.5 (2) C19—C20—C15 120.9 (2)
C9—C8—C5 122.2 (2) C19—C20—H20 119.6
C9—C8—C13 117.6 (2) C18—C21—H21A 109.5
C13—C8—C5 120.2 (2) C18—C21—H21B 109.5
C8—C9—H9 119.5 C18—C21—H21C 109.5
C10—C9—C8 121.0 (2) H21A—C21—H21B 109.5
C10—C9—H9 119.5 H21A—C21—H21C 109.5
C9—C10—H10 119.2 H21B—C21—H21C 109.5
C11—C10—C9 121.5 (2) O—C22—Ni 166.1 (3)
Ni—N1—C3—C2 −174.47 (18) C4—C5—C8—C9 45.6 (4)
Ni—N1—C3—C4 4.0 (3) C4—C5—C8—C13 −135.3 (3)
Ni—N2—C4—C3 −7.8 (2) C5—C6—C7—N2 1.1 (3)
Ni—N2—C4—C5 173.14 (15) C5—C6—C7—C15 178.8 (2)
Ni—N2—C7—C6 −170.94 (18) C5—C8—C9—C10 −177.0 (2)
Ni—N2—C7—C15 11.1 (4) C5—C8—C13—C12 177.7 (2)
N1—Ni—N2—C4 7.95 (17) C6—C5—C8—C9 −135.8 (2)
N1—Ni—N2—C7 177.3 (2) C6—C5—C8—C13 43.2 (3)
N1—Ni—C22—O 0.000 (5) C6—C7—C15—C16 48.5 (3)
N1—C3—C4—N2 2.5 (3) C6—C7—C15—C20 −131.3 (3)
N1—C3—C4—C5 −178.9 (3) C7—N2—C4—C3 179.68 (18)
N2i—Ni—N1—C3i 6.7 (2) C7—N2—C4—C5 0.7 (3)
N2i—Ni—N1—C3 179.2 (2) C7—C15—C16—C17 178.8 (2)
N2—Ni—N1—C3 −6.7 (2) C7—C15—C20—C19 −178.7 (2)
N2—Ni—N1—C3i −179.2 (2) C8—C5—C6—C7 −179.5 (2)
N2i—Ni—N2—C4 31.5 (6) C8—C9—C10—C11 −1.4 (4)
N2i—Ni—N2—C7 −159.1 (3) C9—C8—C13—C12 −3.2 (3)
N2—Ni—C22—O 90.49 (6) C9—C10—C11—C12 −1.8 (4)
N2i—Ni—C22—O −90.49 (6) C9—C10—C11—C14 178.5 (2)
N2—C4—C5—C6 0.0 (3) C10—C11—C12—C13 2.4 (4)
N2—C4—C5—C8 178.8 (2) C11—C12—C13—C8 0.1 (4)
N2—C7—C15—C16 −134.0 (2) C13—C8—C9—C10 3.9 (3)
N2—C7—C15—C20 46.2 (3) C14—C11—C12—C13 −177.8 (2)
C1—C2—C3—N1 1.2 (4) C15—C16—C17—C18 0.3 (4)
C1—C2—C3—C4 −176.9 (3) C16—C15—C20—C19 1.5 (3)
C2i—C1—C2—C3 −0.1 (5) C16—C17—C18—C19 0.8 (4)
C2—C3—C4—N2 −179.3 (2) C16—C17—C18—C21 −179.4 (2)
C2—C3—C4—C5 −0.6 (5) C17—C18—C19—C20 −0.8 (4)
C3i—N1—C3—C2 −2.6 (4) C18—C19—C20—C15 −0.4 (4)
C3i—N1—C3—C4 175.9 (2) C20—C15—C16—C17 −1.4 (3)
C3—C4—C5—C6 −178.7 (3) C21—C18—C19—C20 179.5 (2)
C3—C4—C5—C8 0.1 (5) C22—Ni—N1—C3i −86.2 (2)
C4—N2—C7—C6 −1.1 (3) C22—Ni—N1—C3 86.2 (2)
C4—N2—C7—C15 −179.0 (2) C22—Ni—N2—C4 −152.32 (18)
C4—C5—C6—C7 −0.7 (3) C22—Ni—N2—C7 17.0 (3)