N1—C2 | 1.479 (4) | C24—C25 | 1.361 (5) |
N1—C6 | 1.483 (4) | C24—H24 | 0.9300 |
N1—H11 | 0.89 (4) | C25—C26 | 1.388 (4) |
N1—H12 | 0.88 (4) | C25—H25 | 0.9300 |
C2—C3 | 1.513 (4) | C26—H26 | 0.9300 |
C2—H2A | 0.9700 | O22—C27 | 1.424 (3) |
C2—H2B | 0.9700 | C27—H27A | 0.9600 |
C3—N4 | 1.458 (3) | C27—H27B | 0.9600 |
C3—H3A | 0.9700 | C27—H27C | 0.9600 |
C3—H3B | 0.9700 | C31—C36 | 1.363 (4) |
N4—C21 | 1.418 (3) | C31—C32 | 1.377 (4) |
N4—C5 | 1.470 (4) | C31—C37 | 1.515 (4) |
C5—C6 | 1.508 (4) | C32—C33 | 1.384 (4) |
C5—H5A | 0.9700 | C32—H32 | 0.9300 |
C5—H5B | 0.9700 | C33—C34 | 1.372 (4) |
C6—H6A | 0.9700 | C33—H33 | 0.9300 |
C6—H6B | 0.9700 | C34—C35 | 1.361 (4) |
C21—C26 | 1.387 (4) | C34—Br34 | 1.905 (3) |
C21—C22 | 1.413 (4) | C35—C36 | 1.394 (4) |
C22—O22 | 1.367 (3) | C35—H35 | 0.9300 |
C22—C23 | 1.382 (4) | C36—H36 | 0.9300 |
C23—C24 | 1.390 (4) | C37—O32 | 1.237 (4) |
C23—H23 | 0.9300 | C37—O31 | 1.251 (4) |
C2—N1—C6 | 110.8 (2) | C22—C23—H23 | 119.8 |
C2—N1—H11 | 110 (2) | C24—C23—H23 | 119.8 |
C6—N1—H11 | 112 (2) | C25—C24—C23 | 119.9 (3) |
C2—N1—H12 | 110 (2) | C25—C24—H24 | 120.1 |
C6—N1—H12 | 107 (2) | C23—C24—H24 | 120.1 |
H11—N1—H12 | 106 (3) | C24—C25—C26 | 120.2 (3) |
N1—C2—C3 | 110.6 (2) | C24—C25—H25 | 119.9 |
N1—C2—H2A | 109.5 | C26—C25—H25 | 119.9 |
C3—C2—H2A | 109.5 | C21—C26—C25 | 121.6 (3) |
N1—C2—H2B | 109.5 | C21—C26—H26 | 119.2 |
C3—C2—H2B | 109.5 | C25—C26—H26 | 119.2 |
H2A—C2—H2B | 108.1 | C22—O22—C27 | 117.7 (2) |
N4—C3—C2 | 109.2 (2) | O22—C27—H27A | 109.5 |
N4—C3—H3A | 109.8 | O22—C27—H27B | 109.5 |
C2—C3—H3A | 109.8 | H27A—C27—H27B | 109.5 |
N4—C3—H3B | 109.8 | O22—C27—H27C | 109.5 |
C2—C3—H3B | 109.8 | H27A—C27—H27C | 109.5 |
H3A—C3—H3B | 108.3 | H27B—C27—H27C | 109.5 |
C21—N4—C3 | 116.6 (2) | C36—C31—C32 | 118.4 (3) |
C21—N4—C5 | 113.3 (2) | C36—C31—C37 | 120.4 (3) |
C3—N4—C5 | 110.7 (2) | C32—C31—C37 | 121.2 (3) |
N4—C5—C6 | 110.4 (2) | C31—C32—C33 | 121.0 (3) |
N4—C5—H5A | 109.6 | C31—C32—H32 | 119.5 |
C6—C5—H5A | 109.6 | C33—C32—H32 | 119.5 |
N4—C5—H5B | 109.6 | C34—C33—C32 | 119.1 (3) |
C6—C5—H5B | 109.6 | C34—C33—H33 | 120.4 |
H5A—C5—H5B | 108.1 | C32—C33—H33 | 120.4 |
N1—C6—C5 | 110.7 (2) | C35—C34—C33 | 121.2 (3) |
N1—C6—H6A | 109.5 | C35—C34—Br34 | 119.1 (2) |
C5—C6—H6A | 109.5 | C33—C34—Br34 | 119.7 (2) |
N1—C6—H6B | 109.5 | C34—C35—C36 | 118.5 (3) |
C5—C6—H6B | 109.5 | C34—C35—H35 | 120.7 |
H6A—C6—H6B | 108.1 | C36—C35—H35 | 120.7 |
C26—C21—C22 | 117.5 (2) | C31—C36—C35 | 121.7 (3) |
C26—C21—N4 | 123.4 (2) | C31—C36—H36 | 119.1 |
C22—C21—N4 | 119.0 (2) | C35—C36—H36 | 119.1 |
O22—C22—C23 | 123.8 (2) | O32—C37—O31 | 124.9 (3) |
O22—C22—C21 | 115.9 (2) | O32—C37—C31 | 118.9 (3) |
C23—C22—C21 | 120.3 (2) | O31—C37—C31 | 116.2 (3) |
C22—C23—C24 | 120.5 (3) | ||
C6—N1—C2—C3 | −56.5 (3) | C22—C21—C26—C25 | −0.5 (4) |
N1—C2—C3—N4 | 58.8 (3) | N4—C21—C26—C25 | −177.9 (3) |
C2—C3—N4—C21 | 168.3 (2) | C24—C25—C26—C21 | −1.2 (5) |
C2—C3—N4—C5 | −60.2 (3) | C23—C22—O22—C27 | 9.3 (4) |
C21—N4—C5—C6 | −167.6 (2) | C21—C22—O22—C27 | −172.6 (2) |
C3—N4—C5—C6 | 59.3 (3) | C36—C31—C32—C33 | 0.6 (5) |
C2—N1—C6—C5 | 55.0 (3) | C37—C31—C32—C33 | −178.5 (3) |
N4—C5—C6—N1 | −56.0 (3) | C31—C32—C33—C34 | 0.4 (5) |
C3—N4—C21—C26 | 14.8 (4) | C32—C33—C34—C35 | −1.3 (5) |
C5—N4—C21—C26 | −115.4 (3) | C32—C33—C34—Br34 | 179.8 (2) |
C3—N4—C21—C22 | −162.6 (2) | C33—C34—C35—C36 | 1.1 (6) |
C5—N4—C21—C22 | 67.1 (3) | Br34—C34—C35—C36 | −179.9 (3) |
C26—C21—C22—O22 | −176.2 (2) | C32—C31—C36—C35 | −0.7 (6) |
N4—C21—C22—O22 | 1.4 (4) | C37—C31—C36—C35 | 178.3 (4) |
C26—C21—C22—C23 | 2.0 (4) | C34—C35—C36—C31 | −0.1 (7) |
N4—C21—C22—C23 | 179.6 (2) | C36—C31—C37—O32 | −173.7 (3) |
O22—C22—C23—C24 | 176.1 (3) | C32—C31—C37—O32 | 5.4 (5) |
C21—C22—C23—C24 | −1.9 (4) | C36—C31—C37—O31 | 6.2 (5) |
C22—C23—C24—C25 | 0.2 (5) | C32—C31—C37—O31 | −174.8 (3) |
C23—C24—C25—C26 | 1.4 (5) |