Table 1.
Position | 1a | 2a | 3a | 4a | 5a | 6a | 7a | 8a | 9a | 10a | 11a | 12a | 13c | 14a | 14b |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | 65.2, CH | 76.4, CH | 78.7, CH | 129.06, CHd | 74.3, CH | 32.6, CH2 | 128.5, CH | 65.5, CH | 32.6, CH2 | 58.1, CH | 146.4, C | 127.8, CH | 124.7, CH | 114.7, CH | 113.5, CH |
2 | 43.8, CH2 | 72.3, CH | 72.1, CH | 136.1, CH | 35.1, CH2 | 41.8, CH2 | 135.9, CH | 44.5, CH2 | 40.6, CH2 | 61.3, CH | 176.3, C | 181.4, C | 192.6, C | 167.0, C | 163.5, C |
3 | 72.3, CH | 34.3, CH2 | 77.6, CH | 74.3, CH | 26.2, CH2 | 211.4, C | 74.2, CH | 72.0, CH | 212.1, C | 73.7, CH | 145.5, C | 146.7, C | 72.8, CH | - | - |
4 | 47.1, CH | 41.1, CH | 45.0, CH | 75.0, C | 48.7, CH | 57.4, CH | 76.1, C | 46.7, CH | 54.3, CH | 82.0, C | 135.9, C | 136.0, C | 42.3, CH | 106.8, C | 104.9, C |
5 | 43.5, C | 41.7, C | 40.8, C | 44.6, C | 41.6, C | 43.6, C | 43.5, C | 41.4, C | 43.2, C | 44.5, C | 41.7, C | 46.9, C | 38.8, C | 43.7, C | 41.6, C |
6 | 43.7, CH2 | 43.4, CH2 | 44.7, CH2 | 35.9, CH2 | 48.8, CH2 | 44.2, CH2 | 39.5, CH2 | 42.8, CH2 | 40.7, CH2 | 39.1, CH2 | 33.0, CH2 | 32.9, CH2 | 33.8, CH2 | 29.9, CH2 | 28.2, CH2 |
7 | 128.9, C | 129.3, C | 128.9, C | 129.7, C | 78.9, C | 78.2, C | 78.6, C | 77.3, C | 76.7, C | 77.3, C | 147.5, C | 142.4, C | 139.0, C | 139.9, C | 138.1, C |
8 | 194.4, C | 194.4, C | 194.0, C | 194.1, C | 205.2, C | 203.3, C | 203.6, C | 202.8, C | 201.5, C | 200.0, C | 151.2, C | 148.0, C | 142.2, C | 144.7, C | 142.9, C |
9 | 122.6, CH | 130.7, CH | 130.7, CH | 129.10, CHd | 123.5, CH | 123.2, CH | 124.8, CH | 118.5, CH | 124.3, CH | 126.5, CH | 103.6, C | 174.8, C | 107.4, C | 106.0, CH | 103.8, CH |
10 | 174.0, C | 168.1, C | 167.2, C | 162.1, C | 169.3, C | 166.8, C | 162.2, C | 175.6, C | 167.9, C | 168.7, C | 131.8, C | 161.3, C | 163.9, C | 159.8, C | 157.1, C |
11 | 145.2, C | 146.0, C | 147.2, C | 146.8, C | 33.5, CH | 33.6, CH | 33.6, CH | 35.1, CH | 34.8, CH | 77.3, C | 125.1, C | 124.2, C | 129.2, C | 129.7, C | 127.7, C |
12 | 22.8, CH3 | 22.9, CH3 | 23.0, CH3 | 23.2, CH3 | 15.9, CH3 | 16.4, CH3 | 16.5, CH3 | 16.2, CH3 | 16.1, CH3 | 27.3, CH3 | 172.3, C | 149.5, CH | 173.1, C | 174.9, C | 172.2, C |
13 | 22.3, CH3 | 22.5, CH3 | 22.7, CH3 | 22.8, CH3 | 17.0, CH3 | 16.8, CH3 | 16.9, CH3 | 17.8, CH3 | 18.1, CH3 | 26.6, CH3 | 8.5, CH3 | 7.5, CH3 | 8.5, CH3 | 8.2, CH3 | 8.1, CH3 |
14 | 20.2, CH3 | 18.6, CH3 | 21.5, CH3 | 22.1, CH3 | 19.8, CH3 | 20.6, CH3 | 23.8, CH3 | 25.8, CH3 | 23.1, CH3 | 22.4, CH3 | 29.1, CH3 | 25.9, CH3 | 23.3, CH3 | 24.6, CH3 | 23.9, CH3 |
15 | 12.3, CH3 | 15.4, CH3 | 12.3, CH3 | 19.8, CH3 | 15.1, CH3 | 7.5, CH3 | 19.8, CH3 | 12.5, CH3 | 8.0, CH3 | 21.1, CH3 | 11.3, CH3 | 11.2, CH3 | 10.3, CH3 | 22.3, CH3 | 21.9, CH3 |
-OAc | 169.9, C, | ||||||||||||||
20.8, CH3 |
Recorded in
CD3OD;
DMSO-d6;
CDCl3.
assignments within a column might be interchanged.