Table 4.
Isothermal crystallization parameters for the PLA composites based on the Avrami equation and the crystallization half-time.
Sample | n a | ln(k)a | R sqr | t0.5 (min) | Δt0.5 a (min) |
---|---|---|---|---|---|
Neat PLA | 2.64 | −4.96 | 0.99 | 5.73 | |
PL7/3 | 2.97 | −7.88 | 0.99 | 12.54 | |
PLM1 | 2.64 | −7.58 | 0.99 | 15.39 | |
PLM3 | 2.71 | −8.36 | 0.99 | 19.04 | |
PLM5 | 2.87 | −9.11 | 0.99 | 20.91 | |
PLM7 | 3.03 | −9.98 | 0.99 | 23.78 | |
PLMS1 | 3.06 | −7.65 | 0.99 | 10.84 | 4.55 |
PLMS3 | 3.25 | −8.97 | 0.99 | 14.14 | 4.90 |
PLMS5 | 2.98 | −7.99 | 0.99 | 12.91 | 8.00 |
PLMS7 | 3.05 | −7.95 | 0.99 | 12.03 | 11.75 |
a Δt0.5is the difference between PLM(t0.5) and PLMS(t0.5). (Δt0.5 = PLM(t0.5)−PLMS(t0.5)).