Skip to main content
. 2020 Oct 28;5(44):28632–28636. doi: 10.1021/acsomega.0c03645

Table 1. Synthesis of 2-Arylidenindan-1,3-dione by the Reaction of Indan-1,3-dione with Benzaldehyde under Various Conditions in the Presence of 2-HEAFa.

entry 2-HEAF (mmol) solvent temp. (°C) time yield (%)b
1 0.0   r.t. 72 h 25
2 0.0 EtOH r.t. 24 h 25
3 0.0 EtOH reflux 24 h 25
4 11.2   r.t. 1 min 80
5 5.6   r.t. 1 min 80
6 1.1   r.t. 1 min 85
7 0.1   r.t. 1 min 98
a

Reaction conditions: benzaldehyde (0.25 mmol), indan-1,3-dione (0.25 mmol), and 2-HEAF.

b

Yields refer to the pure isolated products.