Table 3. Adsorption Kinetics Parameters for Tannin Adsorption onto OPT-Derived AC Obtained from the Fitting and Reliability Indicators.
PFO Lagergren63 |
PSO Ho
and McKay55 |
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---|---|---|---|---|---|---|---|---|---|---|
pH | qtexp (mg g–1) | k1 (min–1) | qtcal (mg g–1) | Adj R2 | Δq (%) | k2 [g (mg min)−1] | qtcal (mg g–1) | Adj R2 | Δq (%) | |
linear equation | 2 | 24.71 | 0.0108 | 0.53 | 0.5268 | 7.522 | 0.26 | 24.98 | 0.9990 | 0.083 |
4 | 23.73 | 0.0085 | 1.54 | 0.5912 | 7.195 | 0.07 | 24.01 | 0.9990 | 0.091 | |
6 | 23.22 | 0.0055 | 0.98 | 0.3064 | 7.366 | 0.06 | 23.55 | 0.9990 | 0.108 | |
8 | 22.41 | 0.0079 | 5.32 | 0.7409 | 5.866 | 0.02 | 22.43 | 0.9880 | 0.007 | |
nonlinear equation | 2 | 24.71 | 2.70 | 24.78 | 0.9997 | 0.023 | 0.61 | 24.95 | 0.9995 | 0.075 |
4 | 23.73 | 2.75 | 23.51 | 0.9946 | 0.072 | 0.65 | 23.56 | 0.9987 | 0.054 | |
6 | 22.63 | 2.66 | 23.12 | 0.9935 | 0.033 | 0.44 | 23.28 | 0.9985 | 0.020 | |
8 | 22.41 | 0.85 | 19.98 | 0.8592 | 0.834 | 0.07 | 20.97 | 0.9487 | 0.495 |